1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane

Base Information

• Chemical Name: 1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane
• CAS No.: 1022983-26-1
• Molecular Formula: C₂₅H₃₁N₅O₂S
• Molecular Weight: 465.619
• Mol file: 1022983-26-1.mol

Synonyms:1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane

Chemical Property of 1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane

There total 1 articles about 1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2-chloromethylpyridine hydrochloride (6959-47-3) + 1-(p-toluenesulfonyl)-1,4,7-triazacyclononane (129422-96-4) → 1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane (1022983-26-1)

Guidance literature:

With tetrabutylammomium bromide; sodium carbonate; In acetonitrile; for 22h; Inert atmosphere; Reflux;

DOI:10.1002/chem.201303317

Reference yield: 80.65%

1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane (1022983-26-1) + dichloromethane (75-09-2) + Ni(2+)*2CF3O3S(1-)*2C2H3N → C26H31F3N5NiO5S2(1+)*CF3O3S(1-)*0.5CH2Cl2

Guidance literature:

1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane; Ni⁽²⁺⁾*2CF₃O₃S^(1-)*2C₂H₃N; In tetrahydrofuran; for 4h; Inert atmosphere; Glovebox;

dichloromethane; Inert atmosphere; Glovebox;

DOI:10.1002/chem.201303317

Reference yield: 76.9%

1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane (1022983-26-1) + iron(II) trifluoromethanesulfonate acetonitrile disolvate + dichloromethane (75-09-2) → C26H31F3FeN5O5S2(1+)*CF3O3S(1-)*0.5CH2Cl2

Guidance literature:

1-(p-toluenesulfonyl)-4,7-di(picolyl)-1,4,7-triazacyclononane; iron(II) trifluoromethanesulfonate acetonitrile disolvate; In tetrahydrofuran; for 5h; Inert atmosphere; Glovebox;

dichloromethane; Inert atmosphere; Glovebox;

DOI:10.1002/chem.201303317

upstream raw materials:

2-chloromethylpyridine hydrochloride

1-(p-toluenesulfonyl)-1,4,7-triazacyclononane