ReH(CO)5

Base Information

• Chemical Name: ReH(CO)5
• CAS No.: 15684-00-1
• Molecular Formula: C5O5 Re
• Molecular Weight: 326.259
• Mol file: 15684-00-1.mol

Synonyms:ReH(CO)5

Chemical Property of ReH(CO)5

Chemical Property:

• PSA: 85.35000
• LogP: -1.37050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 326.930325
• Heavy Atom Count: 11
• Complexity: 10

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Re]

Technology Process of ReH(CO)5

There total 18 articles about ReH(CO)5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rhenium + carbon monoxide (201230-82-2) → decacarbonyldirhenium(0) (14285-68-8) + rheniumpentacarbonyl (15684-00-1,53796-42-2)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); solid matrix: CO; not isolated, detected by IR-spectr.;

DOI:10.1016/0022-2860(88)80125-X

Reference yield:

decacarbonyldirhenium(0) (14285-68-8) → rheniumpentacarbonyl (15684-00-1,53796-42-2)

Guidance literature:

With carbon monoxide; In hexane; Irradiation (UV/VIS); 22°C, in 1 atm of CO, flash photplysis;

DOI:10.1021/ja00410a017

Reference yield:

hydridopentacarbonylrhenium(I) (16457-30-0) → rheniumpentacarbonyl (15684-00-1,53796-42-2)

Guidance literature:

In solid matrix; byproducts: HCO radical; Irradiation (UV/VIS); in solid CO;

DOI:10.1021/ja00415a019

upstream raw materials:

decacarbonyldirhenium⁽⁰⁾

carbon monoxide

hydridopentacarbonylrhenium(I)

(CO)5ReRe(CO)3(bpy')

Downstream raw materials:

rhenium(I) pentacarbonyl bromide

rhenium(I) pentacarbonyl chloride

decacarbonyldirhenium⁽⁰⁾

Re(CO)5(NO)C₆H₂(C(CH₃)3)3

Refernces

• 1、 Fawcett, J. Paul,Poe, Anthony,Sharma, Kumud R.. "". . . Retrieved 1979.
• 2、 Gasanov. "Rate constants for reactions of Cl abstraction from CCl4 by CCl3CH2 .CHR radicals and Br abstraction from CCl3CH2CHBrR (R = Bun, AcO, OCNC4H8, CN) by .". . p. 46 - 49. Retrieved 2007/10/03.
• 3、 Yang, Haw,Snee, Preston T.,Kotz, Kenneth T.,Payne, Christine K.,Frei, Heinz,Harris, Charles B.. "Femtosecond infrared studies of a prototypical one-electron oxidative- addition reaction: Chlorine atom abstraction by the Re(CO)s radical [5]". . p. 9227 - 9228. Retrieved 2007/10/03.