Titanium(II) oxide

Base Information

• Chemical Name: Titanium(II) oxide
• CAS No.: 12137-20-1
• Deprecated CAS: 142023-00-5,98226-41-6,98226-42-7,853933-30-9,1309477-91-5,1471346-42-5,853933-30-9,98226-41-6,98226-42-7
• Molecular Formula: OTi
• Molecular Weight: 63.8794
• DSSTox Substance ID: DTXSID7065253
• Wikipedia: Titanium(II) oxide,Titanium(II)_oxide
• Wikidata: Q2985790
• Mol file: 12137-20-1.mol

Synonyms:Titanium(II) oxide;Titanium monoxide;12137-20-1;Oxotitanium;Titanium oxide (TiO);EINECS 235-236-5;MFCD00036279;(oxido)titanium;O-Ti;Titanium oxide, 99.9%;DTXSID7065253;CHEBI:134455;Titanium(II) oxide, optical grade;AKOS025310766;FT-0695211;Q2985790;Titanium(II) oxide, coating quality, granular, 99.5%;Titanium(II) oxide, optical grade, pellets (99.9+%-Ti);Titanium(II) oxide, pieces, >=99.5% trace metals basis;Titanium(II) oxide, powder, -325 mesh, 99.9% trace metals basis

Chemical Property of Titanium(II) oxide

Chemical Property:

• Appearance/Colour: golden yellow
• Melting Point: 1700 °C
• Boiling Point: >3000 °C
• Flash Point: >3000oC
• PSA: 17.07000
• Density: 4.95 g/cm³
• LogP: -0.11880
• Water Solubility.: Soluble in concentrated sulfuric acid, concentrated hydrofluoric acid and alkali. Insoluble in water, diluted sulfuric acid, hyd
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 63.9428553
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Titanium(II) oxide, optical grade, pellets (99.9+%-Ti) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O=[Ti]
• Uses: Used for vacuum deposition. Also applications include sunscreens and UV-blocking in cosmetics, varnishes, wood preservatives, textile fibers, and packaging films. Also used as paint pigment, opacifying agent, welding rod fluxes, optical coatings, as a catalyst, ceramic finish coat, plastics, elastomers, coated fabrics, printing inks, roofing granules, glass, and in glazes. Also identified as Titanium monoxide.

Technology Process of Titanium(II) oxide

There total 53 articles about Titanium(II) oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oxygen (80937-33-3) + titanium(IV) oxide → titanium oxide (12137-20-1) + peroxo titanium monoxide (1344-55-4) + O4Ti2 + disuperoxo titanium monoxide

Guidance literature:

In solid matrix; Irradiation (UV/VIS); in O2/Ar matrix at 6 K; IR;

DOI:10.1021/jp805495d

Reference yield:

titanium nitride + silica gel (112926-00-8,7631-86-9) → titanium oxide (12137-20-1) + silicon monoxide + dinitrogen monoxide (10024-97-2)

Guidance literature:

In gas; high temp. react. with silica gel melt at 2500 K, equil. pressure of gaseous reagents: 1.05E-3 atm;

Reference yield:

titanium(IV) oxide → titanium oxide (12137-20-1)

Guidance literature:

With hydrogen; at 130 at, 2000°C;

upstream raw materials:

titanium

barium(II) acetate

magnesium

samarium

Downstream raw materials:

titanium

titanium chloride

titanium(III) chloride

titanium disilicide

Refernces

• 1、 Ritter, David,Weisshaar, James C.. "Kinetics and Neutral Transition-Metal Atoms in the Gas Phase: Oxidation of Ti(a3F) by NO, O2, and N2O". . p. 1576 - 1581. Retrieved 1989.
• 2、 Choi,Mamak,Ozin,Peiris. "Exploring the thermal transformation of mesoporous titania using spectroscopic ellipsometry". . p. 825 - 828. Retrieved 2008.
• 3、 Koyama, M.,Arai, S.,Suenaga, S.,Nakahashi, M.. "Interfacial reactions between titanium film and single crystal α-Al2O3". . . Retrieved 1993.
• 4、 Kubart,Depla,Martin,Nyberg,Berg. "High rate reactive magnetron sputter deposition of titanium oxide". . . Retrieved 2008.
• 5、 Carette, P.,Schamps, J.. "". . p. 448 - 450. Retrieved 1992.
• 6、 Tanemura,Kajino,Miao,Koide,Tanemura,Toh,Kaneko,Mori. "Fabrication and structural characterization of TiO nanoparticle soft-landed on substrate by the magnetron sputtering-gas aggregation method". . p. 79 - 82. Retrieved 2005.
• 7、 Zhuang, Jia,Li, Zhen Hua,Fan, Kangnian,Zhou, Mingfei. "Matrix isolation spectroscopic and theoretical study of carbon dioxide activation by titanium oxide molecules". . p. 3388 - 3395. Retrieved 2012.
• 8、 Clemmer, D. E.,Honma, K.,Koyano, I.. "Kinetics of Excited-State Ti(a5F) Depletion by NO, O2, N2O, and N2". . p. 11480 - 11488. Retrieved 1993.
• 9、 Li, Shangshu,Zou, Xingli,Zheng, Kai,Lu, Xionggang,Xu, Qian,Chen, Chaoyi,Zhou, Zhongfu. "Direct production of TiAl3 from Ti/Al-containing oxides precursors by solid oxide membrane (SOM) process". . p. 1243 - 1252. Retrieved 2017.
• 10、 Steimle, Timothy C.,Shirley, Jeffrey E.. "". . p. 8000 - 8002. Retrieved 1989.