Benzylidene-2-naphthylamine

Base Information

• Chemical Name: Benzylidene-2-naphthylamine
• CAS No.: 891-32-7
• Molecular Formula: C17H13 N
• Molecular Weight: 231.297
• Hs Code.: 2925290090
• European Community (EC) Number: 660-834-1
• NSC Number: 176099
• DSSTox Substance ID: DTXSID10306409
• Nikkaji Number: J80.006F
• Mol file: 891-32-7.mol

Synonyms:Benzylidene-2-naphthylamine;891-32-7;N-Benzylidenenaphthalen-2-amine;N-naphthalen-2-yl-1-phenylmethanimine;(E)-N-(naphthalen-2-yl)-1-phenylmethanimine;N-Benzylidene-2-naphthylamine;NSC176099;METHYLVIOLETBASE;Benzal-ss-naphthylamin;Benzylidene-2-napthylamine;SCHEMBL3788564;Benzylidine-.beta.-naphthylamine;DTXSID10306409;CKIGNOCMDJFFES-QGOAFFKASA-N;(E)-N-benzylidenenaphthalen-2-amine;MFCD00059551;AKOS000567242;NSC-176099;2-Naphthalenamine, N-(phenylmethylene)-;B0261;CS-0435360;FT-0744603;D88619;N-[(E)-Phenylmethylidene]-2-naphthalenamine #;75472-73-0

Chemical Property of Benzylidene-2-naphthylamine

Chemical Property:

• Melting Point: 101 °C
• Boiling Point: 400.5oC at 760 mmHg
• Flash Point: 188.5oC
• PSA: 12.36000
• Density: 1.02g/cm3
• LogP: 4.59040
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 231.104799419
• Heavy Atom Count: 18
• Complexity: 277

Purity/Quality:

98%,99%, ^*data from raw suppliers

Benzylidene-2-naphthylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=NC2=CC3=CC=CC=C3C=C2

Technology Process of Benzylidene-2-naphthylamine

There total 12 articles about Benzylidene-2-naphthylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

benzaldehyde (100-52-7) + naphthalen-2-ylamine (91-59-8) → benzylidene(2-naphthyl)amine (891-32-7)

Guidance literature:

In benzene; for 2h; Heating;

DOI:10.1023/A:1012355506689

Reference yield: 90.0%

naphthalen-2-ylamine (91-59-8) + benzyl alcohol (100-51-6,185532-71-2) → benzylidene(2-naphthyl)amine (891-32-7)

Guidance literature:

With C₁₉H₃₄MnN₃O₂P₂; In toluene; at 140 ℃; for 16h; Molecular sieve; Inert atmosphere;

DOI:10.1002/chem.201603148

Reference yield: 58.0%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + benzaldehyde (100-52-7) + naphthalen-2-ylamine (91-59-8) → 5-phenyl-1,2,3,4-tetrahydrobenzo[a]phenanthridine (24896-50-2) + benzylidene(2-naphthyl)amine (891-32-7)

Guidance literature:

With racemic methyl phenyl sulfoxide; 10-camphorsufonic acid; oxygen; potassium iodide; In toluene; at 160 ℃; for 0.25h;

DOI:10.1002/cjoc.202100670

upstream raw materials:

ethanol

benzaldehyde

naphthalen-2-ylamine

hydrobenzamide

Downstream raw materials:

N-(morpholin-4-yl-phenyl-methyl)-N-naphthalen-2-yl-benzamide

1-(3-pyridyl)-3-phenylbenzoquinoline

(2RS,3RS)-3-[2]naphthylamino-2,3-diphenyl-propionic acid

3-phenyl-1-[2-(quinolin-2-yl)ethenyl]benzo[f]quinoline

Refernces

• 1、 Jin, Ruo-Xing,Dai, Jing-Cheng,Li, Yan,Wang, Xi-Sheng. "Copper-Catalyzed Intramolecular Amination of C(sp3)-H Bond of Secondary Amines to Access Azacycles". supporting information. p. 421 - 426. Retrieved 2021/01/26.
• 2、 Hu, Yan,Nan, Jiang,Yin, Jiacheng,Huang, Guanjie,Ren, Xin,Ma, Yangmin. "Rhodium-Catalyzed Dehydrogenative Annulation of N-Arylmethanimines with Vinylene Carbonate for Synthesizing Quinolines". supporting information. p. 8527 - 8532. Retrieved 2021/11/13.