5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

Base Information

Chemical Name:5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide
CAS No.:141401-46-9
Molecular Formula:C₂₁H₂₅NO₃S
Molecular Weight:371.5
Hs Code.:

Synonyms:5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

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Chemical Property of 5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

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Technology Process of 5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

There total 5 articles about 5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.4%

: 141401-42-5
5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one

: 141401-46-9
5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

Guidance literature:: With sodium periodate; In methanol; water; for 20h; Ambient temperature;
DOI:10.1248/cpb.40.617

Reference yield:

: 37845-64-0
2-Cyanoethyl 2-(Methylamino)phenyl Sulfide

: 141401-46-9
5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

Guidance literature:: Multi-step reaction with 4 steps

1: K₂CO₃ / tetrahydrofuran

2: 86.2 percent / K₂CO₃, NaBH₄ / dioxane; propan-2-ol / 2 h / 70 - 80 °C

3: 1.) LDA / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, a) -78 deg C, 30 min, b) 0 deg C, 1 h

4: 96.4 percent / NaIO₄ / methanol; H₂O / 20 h / Ambient temperature

With sodium tetrahydroborate; sodium periodate; potassium carbonate; lithium diisopropyl amide; In tetrahydrofuran; 1,4-dioxane; methanol; water; isopropyl alcohol;
DOI:10.1248/cpb.40.617

Reference yield:

: 100-39-0
benzyl bromide

: 141401-46-9
5-benzyl-3-methyl-8-oxa-12-thia-3-aza-1,2-benzocyclododecan-4-one 12-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LDA / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, a) -78 deg C, 30 min, b) 0 deg C, 1 h

2: 96.4 percent / NaIO₄ / methanol; H₂O / 20 h / Ambient temperature

With sodium periodate; lithium diisopropyl amide; In methanol; water;
DOI:10.1248/cpb.40.617