(S)-N-(benzylidene) methyl phenylphosphinamide

Base Information

Chemical Name:(S)-N-(benzylidene) methyl phenylphosphinamide
CAS No.:1208347-16-3
Molecular Formula:C₁₄H₁₄NOP
Molecular Weight:243.245
Hs Code.:

Synonyms:(S)-N-(benzylidene) methyl phenylphosphinamide

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Chemical Property of (S)-N-(benzylidene) methyl phenylphosphinamide

Chemical Property:

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Technology Process of (S)-N-(benzylidene) methyl phenylphosphinamide

There total 6 articles about (S)-N-(benzylidene) methyl phenylphosphinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 54835-97-1
(S)-P-methyl-P-phenylphosphinic amide

: 100-52-7
benzaldehyde

: 1208347-16-3
(S)-N-(benzylidene) methyl phenylphosphinamide

Guidance literature:: With caesium carbonate; In dichloromethane; at 20 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201501260

Reference yield:

: 5761-97-7
methyl(phenyl)phosphinic chloride

: 1208347-16-3
(S)-N-(benzylidene) methyl phenylphosphinamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: triethylamine / tetrahydrofuran / 0.67 h / 0 °C / Inert atmosphere

1.2: 3 h / 0 °C / Inert atmosphere

2.1: sodium; ammonia; Iron(III) nitrate nonahydrate / tetrahydrofuran / Inert atmosphere

3.1: caesium carbonate / dichloromethane / 20 °C / Inert atmosphere

With Iron(III) nitrate nonahydrate; ammonia; sodium; caesium carbonate; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1002/ejoc.201501260

Reference yield:

: 2240-41-7
dimethyl phenylphosphonate

: 1208347-16-3
(S)-N-(benzylidene) methyl phenylphosphinamide

Guidance literature:: Multi-step reaction with 5 steps

1.1: 18 h / Reflux; Inert atmosphere

2.1: phosphorus pentachloride / tetrachloromethane / Inert atmosphere

3.1: pyridine / toluene / 0.67 h / 0 °C / Inert atmosphere

3.2: 3 h / 0 °C / Inert atmosphere

4.1: sodium; ammonia; Iron(III) nitrate nonahydrate / tetrahydrofuran / Inert atmosphere

5.1: caesium carbonate / dichloromethane / 20 °C / Inert atmosphere

With pyridine; Iron(III) nitrate nonahydrate; phosphorus pentachloride; ammonia; sodium; caesium carbonate; In tetrahydrofuran; tetrachloromethane; dichloromethane; toluene;
DOI:10.1002/ejoc.201501260