Platinum, bis(methylamine)dichloro-, cis-

Base Information

• Chemical Name: Platinum, bis(methylamine)dichloro-, cis-
• CAS No.: 15273-32-2
• Molecular Formula: C₂H₁₀Cl₂N₂Pt
• Molecular Weight: 328.101
• Mol file: 15273-32-2.mol

Synonyms:NSC 153154;cis-Di-(methylamine)dichloroplatinum;Platinum cis-dichloro bis(methylamine);cis-Dichlorbis(methylamine)platinum(2+);cis-Dichlorobis(methylamine)platinum(II);Platinum, bis(methylamine)dichloro-, cis-;Platinum, dichlorobis(methylamine)-, cis-;Platinum, bis(methylammine)dichloro-, cis-;Platinum, dichlorobis(methanamine)-, (SP-4-2)-;LS-117719

Chemical Property of Platinum, bis(methylamine)dichloro-, cis-

Chemical Property:

• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 326.986898
• Heavy Atom Count: 7
• Complexity: 2

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN.CN.[Cl-].[Cl-].[Pt+2]

Technology Process of Platinum, bis(methylamine)dichloro-, cis-

There total 19 articles about Platinum, bis(methylamine)dichloro-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

potassium tetrachloroplatinate(II) (10025-99-7) → trans-dichlorobis(methylamine)platinum(II) (15273-32-2,15319-09-2,14096-56-1)

Guidance literature:

With methylamine; HCl; In water; amine and Pt-compound kept at 50°C overnight; filtration; excess of amine evapd. (water-bath); addn. of concd. HCl; heating on water-bath for 1 h; elem. anal.;

DOI:10.1016/S0020-1693(00)83355-1

Reference yield: 87.0%

{platinum(II)(methylamine)4}Cl2 → trans-dichlorobis(methylamine)platinum(II) (15273-32-2,15319-09-2,14096-56-1)

Guidance literature:

With methylamine; In water; placing Pt complex soln. on a boiling water-bath; addn. of equal volume of 25% ethylamine soln. with stirring; heating, 30 min; evapn.; cooling; passing CO2 through soln., 10 min; addn. of concd. HCl; heating to boiling, 2h; addn. of H2O; cooling (ice); separation of ppt.; repeating react. with HCl; suction of crystals from mother liquor; washing (ice-water, alcohol, ether); elem. anal.;

Reference yield: 30.0%

cis-diiodobis(methylamine)platinum(II) (14096-57-2,16580-93-1,33634-55-8) + potassium chloride → cis-[platinum(II)bis(methylamine)dichloride] (15273-32-2,14096-56-1,15319-09-2)

Guidance literature:

cis-diiodobis(methylamine)platinum(II); With silver perchlorate; In water; Darkness;

potassium chloride; In water; at 40 ℃; for 6h;

DOI:10.1039/d0nj00108b

upstream raw materials:

hydrogenchloride

trans-[bis(methylamino)bis(nitrato)platinum(II)]

potassium tetrachloroplatinate(II)

cis-diiodobis(methylamine)platinum(II)

Downstream raw materials:

cis-[Pt(NH₂CH(CH₃)₂)₂Cl₂]

trans-[Pt(MeNH₂)2(1-cyclohexylmethylthyminate-N₃)Cl]

platinum

platinum(II) chloride

Refernces

• 1、 Olusegun, Moses Ariyo,Reddy, Desigan,Jaganyi, Deogratius. "A kinetic and mechanistic study of analogous bifunctional dialkylamine platinum(ii) complexes". . p. 5138 - 5146. Retrieved 2020/04/09.
• 2、 Ermondi, Giuseppe,Caron, Giulia,Ravera, Mauro,Gabano, Elisabetta,Bianco, Sabrina,Platts, James A.,Osella, Domenico. "Molecular interaction fields vs. quantum-mechanical-based descriptors in the modelling of lipophilicity of platinum(iv) complexes". supporting information. p. 3482 - 3489. Retrieved 2013/03/28.