Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

Base Information

Chemical Name:Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)
CAS No.:92787-11-6
Molecular Formula:C₂₀H₂₅N₂O₄Re
Molecular Weight:543.636
Hs Code.:

Re(C<sub>5</sub>(CH<sub>3</sub>)5)(C(O)OCH<sub>3</sub>)(N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>(OCH<sub>3</sub>))(CO)

Synonyms:Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

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Chemical Property of Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

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Technology Process of Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

There total 3 articles about Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 92786-90-8
{Cp*Re(CO)2(p-N₂C₆H₄OMe)}{BF₄}

: 92787-11-6
Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

Guidance literature:: With methanol; In methanol; Schlenk app., N2; Re complex in MeOH at -78°C is treated with K(HB(OCHMe2)3) by syringe, 15 min; solvent is removed at ambient temp. under vac., residue is extd. with hexane-THF, filtered through Celite, pptd. when concd. in vac. and cooledto -78°C; elem. anal.;

Reference yield: 95.0%

: 92786-90-8
{Cp*Re(CO)2(p-N₂C₆H₄OMe)}{BF₄}

: 124-41-4
sodium methylate

: 92787-11-6
Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

Guidance literature:: In acetone; Schlenk app., N2; to a soln. of the Re complex is added NaOMe, mixt. isstirred for 15 min; solvent is removed in vac., CH2Cl2 is added, soln. is filtered, hexane is added; elem. anal.;

Reference yield: 89.0%

: 67-56-1
methanol

: 92786-90-8
{Cp*Re(CO)2(p-N₂C₆H₄OMe)}{BF₄}

: 92787-11-6
Re(C₅(CH₃)5)(C(O)OCH₃)(N₂C₆H₄(OCH₃))(CO)

Guidance literature:: With lithium aluminium tetrahydride; In methanol; N2 or Ar-atmosphere, room temp.; filtering, evapn. (vac.), extg. (hexane);
DOI:10.1021/om00010a032