Bismuth, compound with lithium (1:1)

Base Information

• Chemical Name: Bismuth, compound with lithium (1:1)
• CAS No.: 12048-27-0
• Molecular Formula: Bi.Li
• Molecular Weight: 0
• Mol file: 12048-27-0.mol

Synonyms:bismuth, compound with lithium (1:1);LITHIUM BISMUTHIDE

Chemical Property of Bismuth, compound with lithium (1:1)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.22500

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bismuth, compound with lithium (1:1)

There total 4 articles about Bismuth, compound with lithium (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bismuth (7440-69-9) + lithium (7439-93-2) → BiLi, α (12048-27-0,12338-02-2)

Guidance literature:

In melt; Li, washed with benzene and dried in high vaccum, is mixed with stoichiometric amount of Bi under Ar or Bi; molten together in a closed Fe-vessel at 515°C;;

Reference yield:

bismuth (7440-69-9) + lithium (7439-93-2) → LiBi (12048-27-0,12338-02-2) + lithium bismuthide + Li2Bi

Guidance literature:

In neat (no solvent); two-source vac. evapn. of Bi and Li in glove box onto substrate (quartz plate at < 390 K) under Ar or N2, humidity held at < 10 ppm H2O vapour, to produce thin films 1.5-3.0 μm thick in 30 min of evapn., subsequent annealing (620 K, 12h), cooling; chem. compn. of film determined by ICPS showed varying amts. of Li3Bi, LiBi and Bi depending on the Li concn.;

DOI:10.1016/0025-5408(88)90184-5

Reference yield:

bismuth (7440-69-9) + lithium hydride → LiBi (12048-27-0,12338-02-2)

Guidance literature:

In neat (no solvent); byproducts: H2; grinding Bi and 10-15% excess LiH, heating (402°C); X-ray powder diffraction analysis;

upstream raw materials:

bismuth

lithium