triphenylbismuth(V) diacetate

Base Information

Chemical Name:triphenylbismuth(V) diacetate
CAS No.:28899-97-0
Molecular Formula:C₂₂H₂₁BiO₄
Molecular Weight:558.387
Hs Code.:

Synonyms:triphenylbismuth(V) diacetate

Suppliers and Price of triphenylbismuth(V) diacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of triphenylbismuth(V) diacetate

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of triphenylbismuth(V) diacetate

There total 21 articles about triphenylbismuth(V) diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 603-33-8
triphenylbismuthane

: 28899-97-0,7239-60-3
triphenylbismuth(V) diacetate

Guidance literature:: With tert.-butylhydroperoxide; acetic acid; In diethyl ether; byproducts: (CH3)3COH, H2O; molar ratio Bi(C6H5)3:(CH3)3COOH:CH3COOH = 1:1:2; stirred at room temp.for one day; liquid distd. off at a reduced pressure, product recrystd. from ethyl acetate, elem. anal.;

Reference yield: 96.0%

: 603-33-8
triphenylbismuthane

: 153289-73-7
triphenylbismuth diformate

: 28899-97-0,7239-60-3
triphenylbismuth(V) diacetate

Guidance literature:: With ozone; toluene; In toluene; ozonized oxygen passed into toluene for 1 h at -78°C: green soln.; BiPh3 in toluene added: yellow suspn.; warmed to ambient temp. while being flushed with Ar: yellow soln.; react. mechanism discussed; evapn. under reduced pressure; recrystn. of residue (contg. also the diacetate) from benzene/hexane gave crystals of the pure diformate; elem. anal.;

Reference yield: 94.0%

: 603-33-8
triphenylbismuthane

: 64-19-7,77671-22-8
acetic acid

: 28899-97-0,7239-60-3
triphenylbismuth(V) diacetate

Guidance literature:: With tert.-butylhydroperoxide; In diethyl ether; byproducts: t-BuOH, H2O; t-BuOOH (5 mmol) was added dropwise to a stirred cold (5-10°C) soln. of Ph3Bi (5 mmol) and carboxylic acid (10 mmol) in Et2O; the mixt. was kept in the dark for 24 h at room temp.; the solvent was distd. off under reduced pressure; purifn. by recrystn. (CHCl3/hexane);
DOI:10.1016/j.jorganchem.2005.04.051