(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

Base Information

Chemical Name:(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride
CAS No.:103562-44-3
Molecular Formula:C₄₈H₃₇N₄Rh
Molecular Weight:772.754
Hs Code.:

Synonyms:(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

Suppliers and Price of (5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

There total 46 articles about (5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 16940-66-2
sodium tetrahydroborate

: 205259-72-9
rhodium(III) tetrakis(4-tolyl)porphyrin chloride

: 103562-44-3
(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

Guidance literature:: In methanol; a suspn. of complex in CH3OH and NaBH4 in aq. NaOH were purged with N2 for 15 min, NaBH4 was added, the mixt. was heated at 50°C under N2for 1 h, cooled to 0°C and 0.1 M HCl was aded, stirred at room t emp. for 15 min under N2; ppt. was filtered, washed with water, vac.-dried;
DOI:10.1021/om0507878

Reference yield: 61.0%

: Rh(5,10,15,20-tetratolylporphyrinato dianion)(cycloheptyl)

: 103562-44-3
(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

: 874299-61-3
(benzyl)(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III)

: 628-92-2,45509-99-7
Cycloheptene

Guidance literature:: With Rh₂(5,10,15,20-tetratolylporphyrinato dianion)₂; In benzene-d6; at 120 ℃; for 22h; Reagent/catalyst; Darkness; Sealed tube;
DOI:10.1021/om500313g