Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide

Base Information

• Chemical Name: Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide
• CAS No.: 1443036-49-4
• Molecular Formula: C₁₅H₁₀F₃IO₃S
• Molecular Weight: 454.208
• Hs Code.: 2931599090
• Mol file: 1443036-49-4.mol

Synonyms:1-phenyl-2-(phenyl-λ³-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one

Chemical Property of Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide

Chemical Property:

• Melting Point: 104 °C(dec.)
• Solubility.: soluble in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide

There total 1 articles about Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + 1-phenyl-2-((trifluoromethyl)sulfonyl)ethan-1-one (35896-48-1) → 1-phenyl-2-(phenyl-λ3-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one (1443036-49-4)

Guidance literature:

In acetonitrile; at 0 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ja402455f

Reference yield: 99.0%

2-(4-tolyl)pyrrole (62506-80-3) + 1-phenyl-2-(phenyl-λ3-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one (1443036-49-4) → 2-(p-tolyl)-5-((trifluoromethyl)thio)-1H-pyrrole

Guidance literature:

With copper (II)-fluoride; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 1h; regioselective reaction;

DOI:10.1021/ol503616y

Reference yield: 92.0%

2-(4-chlorophenyl)-1H-pyrrole (19867-89-1) + 1-phenyl-2-(phenyl-λ3-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one (1443036-49-4) → 2-(4-chlorophenyl)-5-((trifluoromethyl)thio)-1H-pyrrole (150618-98-7)

Guidance literature:

With copper (II)-fluoride; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 1h; regioselective reaction;

DOI:10.1021/ol503616y

upstream raw materials:

[bis(acetoxy)iodo]benzene

1-phenyl-2-((trifluoromethyl)sulfonyl)ethan-1-one

Downstream raw materials:

(E)-methyl 3-((4-bromobenzyl)amino)-2-((trifluoromethyl)thio)but-2-enoate

(E)-methyl 3-(benzylamino)-3-(p-tolyl)-2-((trifluoromethyl)thio)acrylate

(E)-methyl 3-(benzylamino)-3-(3-methoxyphenyl)-2-((trifluoromethyl)thio)acrylate

(E)-methyl 3-(benzylamino)-3-(2-methoxyphenyl)-2-((trifluoromethyl)thio)acrylate