trans-{PtCH₃(CN)(PEt₃)2}

Base Information

• Chemical Name: trans-{PtCH₃(CN)(PEt₃)2}
• CAS No.: 22289-45-8
• Molecular Formula: C₁₄H₃₃NP₂Pt
• Molecular Weight: 472.45
• Mol file: 22289-45-8.mol

Synonyms:trans-{PtCH₃(CN)(PEt₃)2}

Chemical Property of trans-{PtCH₃(CN)(PEt₃)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-{PtCH₃(CN)(PEt₃)2}

There total 1 articles about trans-{PtCH₃(CN)(PEt₃)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) → trans-{PtH(CH2CN)(PEt3)2} (118831-46-2) + trans-{PtCH3(CN)(PEt3)2} (22289-45-8) + platinum (7440-06-4)

Guidance literature:

In acetonitrile; benzene; Electrolysis; electrochemically reducing trans-(PtH(Cl)(PEt3)2) at -2.1 V vs Ag/AgCl in CH3CN/C6H6 (5/2, v/v), terminating electrolysis at constancy of current, standing sealed in vacuo for several weeks; 31P NMR;

DOI:10.1021/om00106a032

Reference yield: 48.0%

trans-{PtCH3(CN)(PEt3)2} (22289-45-8) → Pt(CN)2(P(C2H5)3)2 + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + ethene (74-85-1) + platinum (7440-06-4)

Guidance literature:

In decalin; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; Kinetics;

DOI:10.1016/0022-328X(83)80227-7

upstream raw materials:

trans-chlorohydridobis(triethylphosphine)platinum(II)

Downstream raw materials:

methane

ethane

ethene

platinum