1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

Base Information

Chemical Name:1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene
CAS No.:935668-22-7
Molecular Formula:C₁₉H₃₂O₄SSi₂
Molecular Weight:412.698
Hs Code.:

Synonyms:1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

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Chemical Property of 1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

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Technology Process of 1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

There total 5 articles about 1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 4-(4-methoxy-phenylsulfanyl)-3-trimethylsilanyloxy-but-2-enoic acid ethyl ester

: 75-77-4
chloro-trimethyl-silane

: 935668-22-7
1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

Guidance literature:: 4-(4-methoxy-phenylsulfanyl)-3-trimethylsilanyloxy-but-2-enoic acid ethyl ester; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1016/j.tetlet.2007.01.150

Reference yield: 85.0%

: 4-(4-methoxy-phenylsulfanyl)-3-trimethylsilanyloxy-but-2-enoic acid ethyl ester

: 935668-22-7
1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

Guidance literature:: In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1016/j.tet.2008.02.010

Reference yield:

: 696-63-9
4-Methoxybenzenethiol

: 935668-22-7
1-(4-ethoxy-2,4-bis-trimethylsilanyloxy-buta-1,3-dienylsulfanyl)-4-methoxy-benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 81 percent / triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

2.1: 78 percent / triethylamine / benzene / 72 h / 20 °C

3.1: LDA / tetrahydrofuran / 1 h / -78 °C

3.2: 85 percent / tetrahydrofuran / -78 - 20 °C

With triethylamine; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1016/j.tetlet.2007.01.150