benzoylamino-acetic acid allyl ester

Base Information

• Chemical Name: benzoylamino-acetic acid allyl ester
• CAS No.: 132237-19-5
• Molecular Formula: C₁₂H₁₃NO₃
• Molecular Weight: 219.24
• Mol file: 132237-19-5.mol

Synonyms:benzoylamino-acetic acid allyl ester

Chemical Property of benzoylamino-acetic acid allyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzoylamino-acetic acid allyl ester

There total 2 articles about benzoylamino-acetic acid allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Hippuric Acid (495-69-2,140480-84-8,21251-67-2,91787-63-2,66407-11-2) + allyl alcohol (107-18-6) → benzoylamino-acetic acid allyl ester (132237-19-5)

Guidance literature:

Hippuric Acid; With ethyl 2-(tert-butoxycarbonyloxyimino)-2-cyanoacetate; N-ethyl-N,N-diisopropylamine; In ethyl acetate; at 0 - 5 ℃; for 1h;

allyl alcohol; In ethyl acetate; at 0 - 5 ℃; for 2h;

DOI:10.1002/adsc.201200645

Reference yield:

Hippuric Acid (495-69-2,140480-84-8,21251-67-2,91787-63-2,66407-11-2) + allyl bromide (106-95-6) → benzoylamino-acetic acid allyl ester (132237-19-5)

Guidance literature:

With sodium hydroxide; 15-crown-5; Yield given. Multistep reaction; 1.) CH₃CN, water, 20 deg C, 5 min, 2.) CH₃CN, water, 20-25 deg C, 8 h;

DOI:10.1007/BF00766546

Reference yield: 94.4%

benzoylamino-acetic acid allyl ester (132237-19-5) + Dimethyl phosphite (868-85-9) → 3-dimethoxyphosphorylpropyl N-benzoylglycinate (132237-22-0)

Guidance literature:

With di-tert-butyl peroxide; at 135 - 140 ℃; for 6h;

DOI:10.1007/BF00766546

upstream raw materials:

Hippuric Acid

allyl bromide

allyl alcohol

Downstream raw materials:

3-dimethoxyphosphorylpropyl N-benzoylglycinate

N-((2-benzylamino)-2-oxoethyl)benzamide