Cupric sulfate, ammoniated

Base Information

• Chemical Name: Cupric sulfate, ammoniated
• CAS No.: 10380-29-7
• Molecular Formula: CuH₁₂N₄*H₂O*O₄S
• Molecular Weight: 245.747
• European Community (EC) Number: 626-953-8
• UN Number: 3077
• UNII: 5NKQ44K2RN
• DSSTox Substance ID: DTXSID70908605
• Wikipedia: Tetraamminecopper(II)_sulfate
• Wikidata: Q413075
• Mol file: 10380-29-7.mol

Synonyms:10380-29-7;Cupric sulfate, ammoniated;copper;azane;sulfate;hydrate;Ammoniated cupric sulfate;TETRAAMMINECOPPER (II) SULFATE HYDRATE;Tetraamminecopper sulfate monohydrate;Ammoniated cupric sulfate, monohydrate;UNII-5NKQ44K2RN;5NKQ44K2RN;Tetraamminecopper(II) sulfate monohydrate;Ammoniated cupric sulfate monohydrate;Copper(2+), tetraammine-, sulfate (1:1), monohydrate;Tetraamminecopper(ii)sulfate hydrate;CSN (CHRIS Code);CuH12N4.H2O.O4S;CUPRUM AMMONIO-SULPHURICUM;DTXSID70908605;CUPRIC SULPHATE, AMMONIATED;Cu-H12-N4.H2-O.O4-S;NA9110;AKOS015913758;CUPRUM AMMONIO-SULPHURICUM [HPUS];TETRAAMMINECOPPER SULFATE, HYDRATE;TETRAAMMINECOPPER SULPHATE, HYDRATE;AMMONIATED CUPRIC SULPHATE MONOHYDRATE;COPPER TETRAAMMINE SULFATE MONOHYDRATE;TETRAAMMINECOPPER SULPHATE MONOHYDRATE;COPPER TETRAAMMINE SULPHATE MONOHYDRATE;TETRAAMMINECOPPER(2+) SULFATE MONOHYDRATE;TETRAAMMINECOPPER(II) SULPHATE MONOHYDRATE;Copper(2+) sulfate--ammonia--water (1/1/4/1);Q413075;TETRAAMMINECOPPER(2+) SULPHATE MONOHYDRATE;Copper(2), tetraammine-, sulfate (1:1), monohydrate;TETRAAMMINECOPPER(2+) SULFATE (1:1) MONOHYDRATE;TETRAAMMINECOPPER(2+) SULPHATE (1:1) MONOHYDRATE;COPPER(2+), TETRAAMMINE-, SULFATE, HYDRATE (1:1:1);COPPER(2+), TETRAAMMINE-, SULPHATE, HYDRATE (1:1:1);COPPER(2+), TETRAAMMINE-, SULPHATE (1:1), MONOHYDRATE

Chemical Property of Cupric sulfate, ammoniated

Chemical Property:

• Vapor Pressure: 3.35E-05mmHg at 25°C
• Boiling Point: 330 °C at 760 mmHg
• Flash Point: °C
• PSA: 110.83000
• Density: 1.81 g/mL at 25 °C(lit.)
• LogP: 0.97160
• Water Solubility.: 18.5g/100mL H2O (21.5°C) [MER06]
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 244.998088
• Heavy Atom Count: 11
• Complexity: 62.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraamminecopper(II) sulfate monohydrate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,N
• Statements: 36/37/38-51-50
• Safety Statements: 26-37/39-60

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N.N.N.N.O.[O-]S(=O)(=O)[O-].[Cu+2]

Technology Process of Cupric sulfate, ammoniated

There total 6 articles about Cupric sulfate, ammoniated which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

copper(ll) sulfate pentahydrate + ammonia (7664-41-7) + water (7732-18-5) → tetramine copper(II) sulphate monohydrate (53290-09-8,15414-11-6,10380-29-7,22989-83-9)

Guidance literature:

In water; salt dissolved in soln. of NH3 in H2O and stirred 5 min; soln. filtered and MeOH added to filtrate; ppt. sepd. and recrystd. fromH2O at 0 °C, washed with NH3 soln. in EtOH 1:1, MeOH, Et2O and d ried at room temp.;

DOI:10.1002/1522-2675(200208)85:8<2316::AID-HLCA2316>3.0.CO;2-A

Reference yield:

ammonia (7664-41-7) + water (7732-18-5) + copper(II) sulfate (7758-99-8) → tetramminecopper(II) sulfate monohydrate (53290-09-8,10380-29-7,15414-11-6,22989-83-9)

Guidance literature:

In water; passing a stream of NH3 through a cooled satd. CuSO4-soln., crystn.;; washing with aq. NH3, drying over chalk;;

Reference yield:

ammonium carbonate + copper(ll) sulfate pentahydrate → tetramminecopper(II) sulfate monohydrate (53290-09-8,10380-29-7,15414-11-6,22989-83-9)

Guidance literature:

In neat (no solvent); byproducts: CO2, H2O; trituration of 20parts CuSO4*5H2O with 23parts (NH4)2CO3, drying in vac. or at 105°C;;

upstream raw materials:

ammonia

water

copper(II) sulfate

Downstream raw materials:

copper(II) sulfate

tetrammine copper(II) sulphate