(1-Cyanoethyl)trichlorosilane

Base Information

• Chemical Name: (1-Cyanoethyl)trichlorosilane
• CAS No.: 2621-01-4
• Molecular Formula: C3H4 Cl3 N Si
• Molecular Weight: 188.516
• Hs Code.: 2931900090
• European Community (EC) Number: 220-060-3
• DSSTox Substance ID: DTXSID00883870
• Nikkaji Number: J192.125H
• Mol file: 2621-01-4.mol

Synonyms:Propanenitrile, 2-(trichlorosilyl)-;(1-Cyanoethyl)trichlorosilane;2621-01-4;SCHEMBL2685619;2-(Trichlorosilyl)propanenitrile;JHVCHXGNRUSRFD-UHFFFAOYSA-;2-(Trichlorosilyl)propiononitrile;DTXSID00883870;EINECS 220-060-3

Chemical Property of (1-Cyanoethyl)trichlorosilane

Chemical Property:

• Vapor Pressure: 0.401mmHg at 25°C
• Boiling Point: 196.3°Cat760mmHg
• Flash Point: 72.5°C
• PSA: 23.79000
• Density: 1.33g/cm³
• LogP: 2.55538
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 186.917859
• Heavy Atom Count: 8
• Complexity: 120

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C#N)[Si](Cl)(Cl)Cl

Technology Process of (1-Cyanoethyl)trichlorosilane

There total 4 articles about (1-Cyanoethyl)trichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

acrylonitrile (107-13-1,25014-41-9) → NCCHMeSiCl3 (2621-01-4)

Guidance literature:

With trichlorosilane; nickel; In tetrahydrofuran; at 20 - 25 ℃;

DOI:10.1039/c39910001424

Reference yield: 32.0%

acrylonitrile (107-13-1,25014-41-9) → NCCHMeSiCl3 (2621-01-4) + 2-cyanoethyltrichlorosilane (1071-22-3)

Guidance literature:

With trichlorosilane; nickel dichloride; diphenyl(methyl)phosphine oxide; at 90 - 95 ℃; for 10h;

DOI:10.1134/S1070363210050105

Reference yield:

trichlorosilane (10025-78-2) + acrylonitrile (107-13-1,25014-41-9) → NCCHMeSiCl3 (2621-01-4)

Guidance literature:

at 160 ℃; im Stahlrohr;

DOI:10.1246/bcsj.29.326

upstream raw materials:

acrylonitrile

trichlorosilane

Downstream raw materials:

NCCHMeSi(OEt)3

Refernces

• 1、 Boudjouk,Han,Jacobsen,Hauck. "Hydrosilylation catalysed by activated nickel". . p. 1424 - 1425. Retrieved 2007/10/02.