trimethyltriethylditin

Base Information

• Chemical Name: trimethyltriethylditin
• CAS No.: 2935-54-8
• Molecular Formula: C₉H₂₄Sn₂
• Molecular Weight: 369.71
• Mol file: 2935-54-8.mol

Synonyms:trimethyltriethylditin

Chemical Property of trimethyltriethylditin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trimethyltriethylditin

There total 6 articles about trimethyltriethylditin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

(C2H5)3SnC6H4-m-CF3 (17197-31-8) + lithium trimethylstannyl (17946-71-3) → α,α,α-trifluorotoluene (98-08-8) + hexamethyldistannane (661-69-8) + trimethyltriethylditin (2935-54-8) + hexaethyl distannane (993-63-5) + trimethyl(3-(trifluoromethyl)phenyl)stannane (17113-81-4)

Guidance literature:

With tert-butylamine; In tetrahydrofuran; LiSnMe3 added to mixt. of m-CF3C6H4SnEt3 and t-butylamine in THF, stirred at 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products determined by GLC;

DOI:10.1246/bcsj.60.3299

Reference yield: 49.0%

triethyl(phenyl)stannane (878-51-3) + lithium trimethylstannyl (17946-71-3) → trimethyl(phenyl)stannane (934-56-5) + hexamethyldistannane (661-69-8) + trimethyltriethylditin (2935-54-8) + hexaethyl distannane (993-63-5) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In tetrahydrofuran; LiSnMe3 added to PhSnEt3 in THF, stirred at 24°C for 1 h, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products isolated by preparative by GLC;

DOI:10.1246/bcsj.60.3299

Reference yield: 31.0%

1-naphthyltriethylstannane (116159-67-2) + lithium trimethylstannyl (17946-71-3) → naphthalene (91-20-3,71998-51-1,72931-45-4) + hexamethyldistannane (661-69-8) + trimethyltriethylditin (2935-54-8) + 1-(trimethylstannyl)naphthalene (944-85-4)

Guidance literature:

With tert-butylamine; In tetrahydrofuran; LiSnMe3 added to mixt. of (1-naphthyl)SnEt3 and t-butylamine in THF, stirred at 50°C for 30 min, hydrolysis with water; extd. with ether, org. layer dried over Na2SO4; yields of products determined by GLC;

DOI:10.1246/bcsj.60.3299

upstream raw materials:

triethyl(phenyl)stannane

lithium trimethylstannyl

1-naphthyltriethylstannane

trimethylstannyl sodium

Downstream raw materials:

triethylstannyllithium

hexamethyldistannane

tetraethyltin

tetramethylstannane