1-(Trimethylstannyl)naphthalene

Base Information

• Chemical Name: 1-(Trimethylstannyl)naphthalene
• CAS No.: 944-85-4
• Molecular Formula: C13H16Sn
• Molecular Weight: 290.98
• Hs Code.: 2931900090
• Mol file: 944-85-4.mol

Synonyms:trimethyl-naphthalen-1-yl-stannane;napthyltrimethyl stannane;Stannane,trimethyl-1-naphthyl;1-Naphthyltrimethylstannane;Stannane,trimethyl-1-naphthalenyl;1-(Trimethylstannyl)naphthalene;

Chemical Property of 1-(Trimethylstannyl)naphthalene

Chemical Property:

• Vapor Pressure: 0.00116mmHg at 25°C
• Boiling Point: 309.5°C at 760 mmHg
• Flash Point: 144.8°C
• PSA: 0.00000
• LogP: 3.07470

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(Trimethylstannyl)naphthalene

There total 3 articles about 1-(Trimethylstannyl)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.6%

ammonium hydroxide (1336-21-6) + 2-bromonaphthalene (580-13-2) + trimethyltin(IV)chloride (1066-45-1) + tert.-butyl lithium (594-19-4) → 1-(trimethylstannyl)naphthalene (944-85-4) + β-naphthyltrimethylstannane (945-77-7)

Guidance literature:

In 1,4-dioxane; diethyl ether; pentane;

Reference yield: 31.0%

1-naphthyltriethylstannane (116159-67-2) + lithium trimethylstannyl (17946-71-3) → naphthalene (91-20-3,71998-51-1,72931-45-4) + hexamethyldistannane (661-69-8) + trimethyltriethylditin (2935-54-8) + 1-(trimethylstannyl)naphthalene (944-85-4)

Guidance literature:

With tert-butylamine; In tetrahydrofuran; LiSnMe3 added to mixt. of (1-naphthyl)SnEt3 and t-butylamine in THF, stirred at 50°C for 30 min, hydrolysis with water; extd. with ether, org. layer dried over Na2SO4; yields of products determined by GLC;

DOI:10.1246/bcsj.60.3299

Reference yield: 31.0%

1-naphthyltriethylstannane (116159-67-2) + lithium trimethylstannyl (17946-71-3) → naphthalene (91-20-3,71998-51-1,72931-45-4) + 1-(trimethylstannyl)naphthalene (944-85-4)

Guidance literature:

In tetrahydrofuran; LiSnMe3 added to (1-naphthyl)SnEt3 in THF, stirred at 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products determined by GLC;

DOI:10.1246/bcsj.60.3299

upstream raw materials:

ammonium hydroxide

2-bromonaphthalene

trimethyltin(IV)chloride

tert.-butyl lithium

Downstream raw materials:

(2,4-dinitrophenyl)(1-napthyl)diazene

cyclohexyl α-naphthyl ketone

1,1'-bisnaphthalene

trimethyltin(IV)chloride