5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo

Base Information

• Chemical Name: 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo
• CAS No.: 325462-39-3
• Molecular Formula: C₃₇H₈F₁₅MnN₄O
• Molecular Weight: 867.435
• Mol file: 325462-39-3.mol

Synonyms:5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo

Chemical Property of 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo

There total 11 articles about 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

MnIV(5,10,15-tris(pentafluorophenyl)corrole)(BrO3) → 5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V) (325462-39-3)

Guidance literature:

In acetonitrile; at 23 ℃; for 0.0333333h; Irradiation;

DOI:10.1016/j.jinorgbio.2016.08.004

Reference yield:

manganese 5,10,15-tris(pentafluorophenyl)corrole (262280-87-5) → 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo (325462-39-3)

Guidance literature:

With benzaldehyde;

DOI:10.1016/j.cclet.2013.03.029

Reference yield:

5,10,15-tris(pentafluorophenyl)corrole + manganese (II) acetate tetrahydrate (6156-78-1) + ozone (10028-15-6) → 5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V) (325462-39-3)

Guidance literature:

With oxygen; In dichloromethane; solns. of org. compd. and Mn salt cooled in dry ice/acetone bath was purged with stream of O2/O3 until color change; mixt., purged with N2, solvent evapd. at - 78°C;

upstream raw materials:

manganese (II) acetate tetrahydrate

ozone

(5,10,15-tris(pentafluorophenyl)corrole^(3-))Mn(V)=NTs

water

Downstream raw materials:

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III)

5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III)