5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III)

Base Information

• Chemical Name: 5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III)
• CAS No.: 918776-46-2
• Molecular Formula: C₄₁H₁₆F₁₅MnN₄O₂
• Molecular Weight: 936.518
• Mol file: 918776-46-2.mol

Synonyms:

Chemical Property of 5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III)

There total 2 articles about 5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

5,10,15-tris(pentafluorophenyl)corrole (238402-21-6) + manganese (II) acetate tetrahydrate (6156-78-1) + ethyl acetate (141-78-6) → 5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III) (918776-46-2)

Guidance literature:

In N,N-dimethyl-formamide; refluxing DMF soln. of manganese compd. and corrole deriv. for 10 min; evapn., dissolving in CH2Cl2 with silica gel, chromy. (silica gel, hexane/ethyl acetate (10:1)), recrystn. (hot n-hexane), MS and UV;

DOI:10.1021/ja1050296

Reference yield:

5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V) (325462-39-3) + ethyl acetate (141-78-6) → 5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III) (918776-46-2)

Guidance literature:

With CH₃C₆H₄SCH₃; In ethyl acetate; byproducts: CH3C6H4S(O)CH3; mixing ethyl acetate solns. of manganese compd. and thioanisole deriv. at 20°C; UV monitoring; Kinetics;

DOI:10.1021/ja1050296

Reference yield: 85.0%

5,10,15-tris(pentafluorophenyl)corrolato(ehyl acetate)manganese(III) (918776-46-2) + bromine (7726-95-6) + ethyl acetate (141-78-6) → 2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(pentafluorophenyl)corrolato(ethyl acetate)manganese(III)

Guidance literature:

In methanol; addn. of methanolic soln. of bromine to methanolic soln. of manganese compd., stirring at room temp. overnight; evapn. at room temp., chromy. (silica gel, hexane/ethyl acetate (10:1)),MS and UV;

DOI:10.1021/ja1050296

upstream raw materials:

5,10,15-tris(pentafluorophenyl)corrole

manganese (II) acetate tetrahydrate

ethyl acetate

5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V)

Downstream raw materials:

5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V)