tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

Base Information

Chemical Name:tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane
CAS No.:1442433-17-1
Molecular Formula:C₂₆H₃₆O₃Si
Molecular Weight:424.656
Hs Code.:

Synonyms:tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

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Technology Process of tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

There total 5 articles about tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₅H₃₄O₄Si

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1442433-17-1
tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

Guidance literature:: With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 - 0 ℃; for 4h;
DOI:10.1016/j.tetlet.2013.04.069

Reference yield:

: 118231-26-8
C₂₄H₃₂O₃Si

: 1442433-17-1
tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

Guidance literature:: Multi-step reaction with 5 steps

1: C₄₈H₅₄N₆O₄; potassium carbonate; potassium osmate(VI) dihydrate; C₆FeN₆^(3-)*2K⁽¹⁺⁾; methanesulfonamide / tert-butyl alcohol; water / 24 h / 0 °C

2: camphor-10-sulfonic acid / dichloromethane / 3 h / 20 °C

3: diisobutylaluminium hydride / dichloromethane / 0.5 h / 0 °C

4: Dess-Martin periodane / dichloromethane / 2 h / 20 °C

5: sodium hexamethyldisilazane / tetrahydrofuran / 4 h / -78 - 0 °C

With potassium osmate(VI) dihydrate; methanesulfonamide; camphor-10-sulfonic acid; C₄₈H₅₄N₆O₄; C₆FeN₆^(3-)*2K⁽¹⁺⁾; sodium hexamethyldisilazane; diisobutylaluminium hydride; potassium carbonate; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; water; tert-butyl alcohol;
DOI:10.1016/j.tetlet.2013.04.069

Reference yield:

: 1442433-15-9
(4R,5S)-ethyl-5-(3-(tert-butyldiphenylsilyloxy)propyl)-2,2-di-methyl-1,3-dioxolane-4-carboxylate

: 1442433-17-1
tert-butyl (3-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)propoxy)diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / dichloromethane / 0.5 h / 0 °C

2: Dess-Martin periodane / dichloromethane / 2 h / 20 °C

3: sodium hexamethyldisilazane / tetrahydrofuran / 4 h / -78 - 0 °C

With sodium hexamethyldisilazane; diisobutylaluminium hydride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tetlet.2013.04.069