(μ-α,α-toluenedithiolato)bis(tricarbonyliron)

Base Information

Chemical Name:(μ-α,α-toluenedithiolato)bis(tricarbonyliron)
CAS No.:105472-01-3
Molecular Formula:C₁₃H₆Fe₂O₆S₂
Molecular Weight:434.013
Hs Code.:

Synonyms:(μ-α,α-toluenedithiolato)bis(tricarbonyliron)

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Chemical Property of (μ-α,α-toluenedithiolato)bis(tricarbonyliron)

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Technology Process of (μ-α,α-toluenedithiolato)bis(tricarbonyliron)

There total 1 articles about (μ-α,α-toluenedithiolato)bis(tricarbonyliron) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

: 17685-52-8
triiron dodecarbonyl

: 78872-76-1
phenylmethane dithiol

: 105472-01-3
(μ-α,α-toluenedithiolato)bis(tricarbonyliron)

Guidance literature:: In tetrahydrofuran; a mixt. of Fe3(CO)12 and the dithiol in THF was reflux gently for 1 h under N2 atm.;; solvent was removed, red oil was subjected to filtration chromy. (silicic acid/pentane); elem. anal.;;
DOI:10.1021/om00145a009

Reference yield: 61.0%

: 105472-01-3
(μ-α,α-toluenedithiolato)bis(tricarbonyliron)

: 75-03-6
ethyl iodide

: 105472-13-7
(C₆H₅CC₂H₅S₂)Fe₂(CO)6

Guidance literature:: With lithium diisopropylamide; In tetrahydrofuran; to a soln. of the complex in THF under N2 at -78°C LDA was added, mixt. was stirred for 25 min at this temp.; EtI was added, soln. was removed from a cold bath and stirred for 1.5 h;; solvent was removed, oil was taken up in pentane and applied to filtration chromy (silicic acid), eluent pentane-CH2Cl2; elem. anal.;;
DOI:10.1021/om00145a009