2-PHENOXYETHYL ACRYLATE

Base Information

• Chemical Name: 2-PHENOXYETHYL ACRYLATE
• CAS No.: 48145-04-6
• Deprecated CAS: 93615-54-4,329327-80-2,1174171-02-8,1000678-29-4,1000678-29-4,1174171-02-8,329327-80-2
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Hs Code.: 2916129000
• European Community (EC) Number: 256-360-6,500-133-9
• UNII: N95C96I48M
• DSSTox Substance ID: DTXSID4040715
• Nikkaji Number: J78.161D
• Wikidata: Q27284726
• ChEMBL ID: CHEMBL1596010
• Mol file: 48145-04-6.mol

Synonyms:AMP 10G;Ageflex PEA;EM 210;Ebecryl 114;Eternal PEA;Ethylene glycol monophenyl ether monoacrylate;Ethylene glycolphenyl ether acrylate;GX 8079;IRR 169;Kayarad R 561;Laromer POEA;Light Ester PO-A;NK Ester AMP 10G;Photomer 4035;SR 339;SR 339A;Sartomer 339;Sartomer SR 339;Viscoat 192;

Chemical Property of 2-PHENOXYETHYL ACRYLATE

Chemical Property:

• Vapor Pressure: 0.005mmHg at 25°C
• Refractive Index: n20/D 1.518(lit.)
• Boiling Point: 295.3 °C at 760 mmHg
• Flash Point: 119.7 °C
• PSA: 35.53000
• Density: 1.079 g/cm³
• LogP: 1.79460
• Storage Temp.: 2-8°C
• Solubility.: Practically insoluble in water
• Water Solubility.: 525mg/L at 25℃
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 192.078644241
• Heavy Atom Count: 14
• Complexity: 183

Purity/Quality:

99% ^*data from raw suppliers

2-PhenoxyethylAcrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi, N
• Hazard Codes: Xi,N
• Statements: 36/37/38-51/53
• Safety Statements: 26-28-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCCOC1=CC=CC=C1
• Uses: 2-Phenoxyethyl Acrylate is used as a monomer in multifunctional and shape memory polymers. Ethylene glycol phenyl ether acrylate (PA) monomer may be used to fabricate polymerization induced grating pattern on photopolymer films.

Technology Process of 2-PHENOXYETHYL ACRYLATE

There total 4 articles about 2-PHENOXYETHYL ACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2-phenoxyethyl acrylate (48145-04-6)

Guidance literature:

With dmap; oxo[hexa(trifluoroacetato)]tetrazinc; In neat (no solvent); at 80 ℃; for 24h; chemoselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejoc.201600737

Reference yield: 90.0%

2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) + acryloyl chloride (814-68-6,25189-84-8) → 2-phenoxyethyl acrylate (48145-04-6)

Guidance literature:

at 0 ℃; for 8h;

DOI:10.1039/c4ra05354k

Reference yield:

2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) + sodium carbonate (497-19-8) + acryloyl chloride (814-68-6,25189-84-8) → 2-phenoxyethyl acrylate (48145-04-6)

Guidance literature:

copper(I) chloride; In benzene;

upstream raw materials:

2-Phenoxyethanol

acrylic acid methyl ester

ethyl acrylate

acryloyl chloride

Downstream raw materials:

1-(3-phenyl-2-propenoyloxy)-2-phenoxyethane

2-phenoxyethyl 3-(1-methyl-1H-indol-3-yl)propanoate

2-phenoxyethyl 2-iodoacrylate

C₂₃H₂₀N₂O₄

Refernces

• 1、 Nakatake, Daiki,Yazaki, Ryo,Ohshima, Takashi. "Chemoselective Transesterification of Acrylate Derivatives for Functionalized Monomer Synthesis Using a Hard Zinc Alkoxide Generation Strategy". supporting information. p. 3696 - 3699. Retrieved 2016/08/20.