methyl bis(chloromethyl)phosphinate

Base Information

• Chemical Name: methyl bis(chloromethyl)phosphinate
• CAS No.: 14212-91-0
• Molecular Formula: C₃H₇Cl₂O₂P
• Molecular Weight: 176.967
• Mol file: 14212-91-0.mol

Synonyms:

Chemical Property of methyl bis(chloromethyl)phosphinate

Chemical Property:

• Vapor Pressure: 0.39mmHg at 25°C
• Boiling Point: 203.7°C at 760 mmHg
• Flash Point: 49.6°C
• Density: 1.347g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl bis(chloromethyl)phosphinate

There total 3 articles about methyl bis(chloromethyl)phosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methanol (67-56-1) + bis(chloromethyl)phosphinic chloride (13482-64-9) → Bis-chlormethyl-phosphinsaeure-methylester (14212-91-0)

Guidance literature:

With triethylamine; In benzene; at 20 ℃; for 6h;

Reference yield: 34.0%

Trimethylmethoxysilane (1825-61-2) + bis(chloromethyl)phosphinic chloride (13482-64-9) → Bis-chlormethyl-phosphinsaeure-methylester (14212-91-0)

Guidance literature:

at 120 ℃; for 1h;

Reference yield:

→ Bis-chlormethyl-phosphinsaeure-methylester (14212-91-0)

Guidance literature:

Saeurechlorid I, CH3OH;

upstream raw materials:

methanol

bis(chloromethyl)phosphinic chloride

Trimethylmethoxysilane

Refernces

• 1、 Saakyan. "Reaction of (chloromethyl)phosphonic(-phosphinic) chlorides with silylated protic nucleophiles". . p. 1712 - 1716. Retrieved 2007/10/03.