{N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(2-)}dipyridineplatinum(II)

Base Information

• Chemical Name: {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(2-)}dipyridineplatinum(II)
• CAS No.: 92181-58-3
• Molecular Formula: C₂₄H₁₆F₈N₄Pt
• Molecular Weight: 707.485

Synonyms:{N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(2-)}dipyridineplatinum(II)

Chemical Property of {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(2-)}dipyridineplatinum(II)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(2-)}dipyridineplatinum(II)

There total 7 articles about {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(2-)}dipyridineplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

pyridine (110-86-1) + dichloro(ethylenediamine)platinum(II) (14096-51-6) + Pentafluorobenzene (363-72-4) → {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(2-)}dipyridineplatinum(II) (92181-58-3) + carbon dioxide (124-38-9,18923-20-1)

Guidance literature:

With K₂CO₃; In pyridine; N2-atmosphere; stirring (115°C, 1 h); evapn. (vac.), light petroleum addn., stirring (1 h), decanting, extg. (Me2CO), filtering, concg., light petroleum addn., crystn. on concg., re crystn. (Me2CO / light petroleum);

DOI:10.1016/S0277-5387(97)00310-0

Reference yield: 42.0%

dichloro(ethylenediamine)platinum(II) (14096-51-6) + thallium(I) pentafluorobenzoate (68558-86-1) + Pentafluorobenzene (363-72-4) → {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(2-)}dipyridineplatinum(II) (92181-58-3)

Guidance literature:

In pyridine; TlO2CC6F5 and Pt(en)Cl2 and HC6F5 were stirred together in pyridine under N2 at 95-115°C for 27 min; pyridine was evapd., residue was stirred with light petroleum to removetraces of pyridine, then was extd. with ether, extract was filtered, residue was evapd. and crystd.; elem. anal.;

Reference yield: 30.0%

bis-iodo{N-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diamine}platinum(II) (135389-34-3) + Pentafluorobenzene (363-72-4) → {N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(2-)}dipyridineplatinum(II) (92181-58-3)

Guidance literature:

With TlO₂CC₆F₄H; In pyridine; byproducts: CO2; (N2), heated at 105-107°C with stirring for 25 min; evapd. to dryness in vacuo, washed with petrol, extracted (acetone), filtered, evapd., recrystd. from ether-petrol, IR, mass spectra;

DOI:10.1016/S0277-5387(00)83764-X

upstream raw materials:

dichloro(ethylenediamine)platinum(II)

thallium(I) pentafluorobenzoate

Pentafluorobenzene

cis-(ethylenediamine)diiodoplatinum(II)

Downstream raw materials:

cis,trans,cis-[N,N?'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato]chlorohydroxydipyridineplatinum(IV)

cis,trans,cis-[N,N?'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato]dihydroxydipyridineplatinum(IV)

cis,trans,cis-[N,N'-bis(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato]dichlorodipyridineplatinum(IV)

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