10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Base Information

Chemical Name:10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine
CAS No.:1392069-92-9
Molecular Formula:C₃₉H₃₇NSSi
Molecular Weight:579.881
Hs Code.:

Synonyms:10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Suppliers and Price of 10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

There total 5 articles about 10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1392069-90-7
3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

: 1066-54-2
trimethylsilylacetylene

: 1392069-92-9
10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 70 ℃; for 6h; Inert atmosphere; Sealed tube;
DOI:10.1007/s11164-012-0642-6

Reference yield:

: 1392069-84-9
3-[(1E)-3,3-diethyltriaz-1-en-1-yl]-10-phenyl-10H-phenothiazine

: 1392069-92-9
10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Guidance literature:: Multi-step reaction with 4 steps

1: methyl iodide; iodine / toluene / 2 h / 55 °C / Inert atmosphere; Sealed tube

2: [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II); potassium acetate / dimethyl sulfoxide / 1 h / 80 °C / Inert atmosphere

3: palladium diacetate; caesium carbonate / N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere

4: bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine; copper(l) iodide / tetrahydrofuran / 6 h / 70 °C / Inert atmosphere; Sealed tube

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II); iodine; potassium acetate; palladium diacetate; caesium carbonate; N-ethyl-N,N-diisopropylamine; methyl iodide; In tetrahydrofuran; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene;
DOI:10.1007/s11164-012-0642-6

Reference yield:

: 1333324-92-7
10-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10H-phenothiazine

: 1392069-92-9
10-phenyl-3-{2,2',6,6'-tetramethyl-4'-[(trimethylsilyl)ethynyl]biphenyl-4-yl}-10H-phenothiazine

Guidance literature:: Multi-step reaction with 2 steps

1: palladium diacetate; caesium carbonate / N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere

2: bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine; copper(l) iodide / tetrahydrofuran / 6 h / 70 °C / Inert atmosphere; Sealed tube

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; palladium diacetate; caesium carbonate; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1007/s11164-012-0642-6