3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

Base Information

Chemical Name:3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine
CAS No.:1392069-90-7
Molecular Formula:C₃₄H₂₈INS
Molecular Weight:609.574
Hs Code.:

Synonyms:3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

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Chemical Property of 3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

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Technology Process of 3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

There total 4 articles about 3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1333324-92-7
10-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10H-phenothiazine

: 22409-77-4
4,4′-diiodo-2,2′,6,6′-tetramethyl-1,1′-biphenyl

: 1392069-90-7
3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

Guidance literature:: With palladium diacetate; caesium carbonate; In N,N-dimethyl-formamide; at 110 ℃; for 1h; Inert atmosphere;
DOI:10.1007/s11164-012-0642-6

Reference yield:

: 1392069-86-1
3-iodo-10-phenyl-10H-phenothiazine

: 1392069-90-7
3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

Guidance literature:: Multi-step reaction with 2 steps

1: [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II); potassium acetate / dimethyl sulfoxide / 1 h / 80 °C / Inert atmosphere

2: palladium diacetate; caesium carbonate / N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere

With [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II); potassium acetate; palladium diacetate; caesium carbonate; In dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1007/s11164-012-0642-6

Reference yield:

: 18073-95-5
3-amino-10-phenyl-10H-phenothiazine

: 1392069-90-7
3-(4'-iodo-2,2',6,6'-tetramethylbiphenyl-4-yl)-10-phenyl-10H-phenothiazine

Guidance literature:: Multi-step reaction with 4 steps

1.1: boron trifluoride diethyl etherate / dichloromethane / 0.67 h / 0 °C / Inert atmosphere

1.2: 1 h / 0 °C / Inert atmosphere

1.3: 20 h / 20 °C / Inert atmosphere

2.1: methyl iodide; iodine / toluene / 2 h / 55 °C / Inert atmosphere; Sealed tube

3.1: [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II); potassium acetate / dimethyl sulfoxide / 1 h / 80 °C / Inert atmosphere

4.1: palladium diacetate; caesium carbonate / N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere

With [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II); boron trifluoride diethyl etherate; iodine; potassium acetate; palladium diacetate; caesium carbonate; methyl iodide; In dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene;
DOI:10.1007/s11164-012-0642-6