(E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

Base Information

• Chemical Name: (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
• CAS No.: 1032938-02-5
• Molecular Formula: C₁₈H₃₆OSi₄
• Molecular Weight: 380.825
• Mol file: 1032938-02-5.mol

Synonyms:(E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

Chemical Property of (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

There total 4 articles about (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

morpholine (110-91-8,99108-56-2) + 4-Methoxystyrene (637-69-4,24936-44-5) + tris-(trimethylsilyl)silane (1873-77-4) → (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane (1032938-02-5) + 4-(2-(1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilan-2-yl)-1-(4-methoxyphenyl)ethyl)morpholine + 2-(4-methoxyphenethyl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

Guidance literature:

With di-tert-butyl peroxide; iron(II) chloride; at 120 ℃; for 20h; Reagent/catalyst; Temperature; Overall yield = 67 %; Overall yield = 62.6 mg; Catalytic behavior; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.201702349

Reference yield: 64.0%

tris-(trimethylsilyl)silane (1873-77-4) + (E)-4-[2-(phenylsulfonyl)vinyl]anisole (87891-80-3) → (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane (1032938-02-5)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In benzene; at 85 ℃; for 4h;

DOI:10.1016/j.tet.2008.03.024

Reference yield: 63.0%

tris-(trimethylsilyl)silane (1873-77-4) + p-ethylanisole (1515-95-3) → (E)-2-(4-methoxystyryl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane (1032938-02-5)

Guidance literature:

p-ethylanisole; With copper diacetate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; at 120 ℃; for 4h; Schlenk technique; Inert atmosphere;

tris-(trimethylsilyl)silane; With pyridine; di-tert-butyl peroxide; at 120 ℃; for 20h; Schlenk technique; Inert atmosphere;

DOI:10.1002/cjoc.202000118

upstream raw materials:

tris-(trimethylsilyl)silane

(E)-4-[2-(phenylsulfonyl)vinyl]anisole

4-methoxyphenylacetylen

morpholine

Downstream raw materials:

E-1-(phenyl)-2-(4'-methoxyphenyl)ethene

(E,E)-1-(4-methoxyphenyl)-4-phenyl-1,3-butadiene