2,4-dinitrobenzenethiolate anion

Base Information

• Chemical Name: 2,4-dinitrobenzenethiolate anion
• CAS No.: 56437-88-8
• Molecular Formula: C₆H₃N₂O₄S
• Molecular Weight: 199.167
• Mol file: 56437-88-8.mol

Synonyms:2,4-dinitrobenzenethiolate anion

Chemical Property of 2,4-dinitrobenzenethiolate anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-dinitrobenzenethiolate anion

There total 46 articles about 2,4-dinitrobenzenethiolate anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

O-ethyl S-(2,4-dinitrophenyl) thiocarbonate (134906-71-1) → ethanol (64-17-5) + carbon dioxide (124-38-9,18923-20-1) + 2,4-dinitrobenzenethiolate anion (56437-88-8)

Guidance literature:

With Quinuclidine; water; at 25 ℃; pH=8.5; Further Variations:; pH-values; Reagents; Kinetics;

DOI:10.1021/jo991036g

Reference yield:

S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate (14793-27-2) → 2,4-dinitrobenzenethiolate anion (56437-88-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiCl / acetone / 4 h / 20 °C

2: potassium bicarbonate buffer / 23 °C / pH 10

With lithium chloride; In acetone;

DOI:10.1039/b707205h

Reference yield:

2,4-dinitrobenzenesulfenyl chloride (528-76-7) → 2,4-dinitrobenzenethiolate anion (56437-88-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 73 percent / CH₂Cl₂ / 2 h / 20 °C

2: LiCl / acetone / 4 h / 20 °C

3: potassium bicarbonate buffer / 23 °C / pH 10

With lithium chloride; In dichloromethane; acetone;

DOI:10.1039/b707205h

upstream raw materials:

piperidine

O-ethyl S-(2,4-dinitrophenyl) dithiocarbonate

morpholine

piperazine