S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate

Base Information

• Chemical Name: S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate
• CAS No.: 14793-27-2
• Molecular Formula: C₈H₉N₂O₇PS
• Molecular Weight: 308.208
• Mol file: 14793-27-2.mol

Synonyms:S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate

Chemical Property of S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate

There total 1 articles about S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

2,4-dinitrobenzenesulfenyl chloride (528-76-7) + phosphorous acid trimethyl ester (121-45-9) → S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate (14793-27-2)

Guidance literature:

In dichloromethane; at 20 ℃; for 2h;

DOI:10.1039/b707205h

Reference yield:

S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate (14793-27-2) → lithium S-(2,4-dinitrophenyl) O-methyl phosphorothiolate

Guidance literature:

With lithium chloride; In acetone; at 20 ℃; for 4h;

DOI:10.1039/b707205h

Reference yield:

S-(2,4-dinitrophenyl) O,'O-dimethyl phosphorothiolate (14793-27-2) → 2,4-dinitrobenzenethiolate anion (56437-88-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiCl / acetone / 4 h / 20 °C

2: potassium bicarbonate buffer / 23 °C / pH 10

With lithium chloride; In acetone;

DOI:10.1039/b707205h

upstream raw materials:

2,4-dinitrobenzenesulfenyl chloride

phosphorous acid trimethyl ester

Downstream raw materials:

2,4-dinitrobenzenethiolate anion