[Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

Base Information

Chemical Name:[Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]
CAS No.:882534-79-4
Molecular Formula:C₂₂H₄₂ClNPTi*C₂₄BF₂₀
Molecular Weight:1113.93
Hs Code.:

[Cp(*)((t)Bu<sub>3</sub>P=N)TiCl][B(C<sub>6</sub>F<sub>5</sub>)4]

Synonyms:[Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

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Chemical Property of [Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

Chemical Property:

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Technology Process of [Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

There total 3 articles about [Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 532434-89-2
[(η5-C5Me5)TiMe2(NP(C(CH3)3)3)]

: 1333-74-0
hydrogen

: 108-90-7
chlorobenzene

: trityl tetrakis(pentafluorophenyl)borate

: 882534-79-4
[Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

Guidance literature:: In chlorobenzene; byproducts: C6H6, (C6H5)2; High Pressure; (Ar); a soln. of Ti complex added dropwise to a soln. of B complex at room temp., shaken for ca 1 min, evacuated, charged with H2 at ca 4 atm, agitated; concd. (vac.), pptd. (hexanes), decanted, dried (vac.); elem. anal.;
DOI:10.1021/ja0583618

Reference yield: 51.0%

: 882534-84-1
[Cp(*)((t)Bu₃P=N)Ti(2-Cl-C₆H₄)][B(C₆F₅)4]

: 882534-79-4
[Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

: 882534-92-1
[(C₅(CH₃)5)(((CH₃)3C)3PNC₆H₄)TiCl]⁽¹⁺⁾*[B(C₆F₅)4]^(1-)=[(C₅(CH₃)5)(((CH₃)3C)3PNC₆H₄)TiCl][B(C₆F₅)4]

Guidance literature:: In chlorobenzene; (Ar); stirred at room temp. for 3 d; hexanes added, crystd. at -30°C; elem. anal.;
DOI:10.1021/ja0583618

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 700846-88-4
[Ti(C₅Me₅)((t-Bu)3PN)CH₃][B(C₆F₅)4]

: 108-90-7
chlorobenzene

: 700846-84-0
[Ti(C₅Me₅)((t-Bu)3PN)(Br)][B(C₆F₅)4]

: 882534-79-4
[Cp(*)((t)Bu₃P=N)TiCl][B(C₆F₅)4]

Guidance literature:: With H₂; In further solvent(s); High Pressure; competition expt.; under 4 atm of H2 in C6H5Cl/C6H5Br; not isolated, detected by NMR;
DOI:10.1021/ja0583618