FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)][B(C₆H₅)4]

Base Information

• Chemical Name: FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)][B(C₆H₅)4]
• CAS No.: 54477-77-9
• Molecular Formula: C₂₄H₂₀B*C₄₃H₄₃FeOP₄
• Molecular Weight: 1074.79
• Mol file: 54477-77-9.mol

Synonyms:FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)][B(C₆H₅)4]

Chemical Property of FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)][B(C₆H₅)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)][B(C₆H₅)4]

There total 7 articles about FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[FeH(CO)(P(CH₂CH₂P(C₆H₅)2)3)][B(C₆H₅)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[(P(CH2CH2PPh2)3)Fe(H)(η(1)-N2)][BPh4] (54477-71-3) + carbon monoxide (201230-82-2) → FeH(CO)(P(CH2CH2P(C6H5)2)3)(1+)*B(C6H5)4(1-)=[FeH(CO)(P(CH2CH2P(C6H5)2)3)][B(C6H5)4] (54477-77-9)

Guidance literature:

In tetrahydrofuran; absence of air and moisture; bubbling CO at 0°C for 4 h; addn. of EtOH, crystn. on slow concn. (CO-stream); elem. anal.;

DOI:10.1021/ic960736q

Reference yield: 90.0%

[FeH2(P(CH2CH2P(C6H5)2)3)] (128973-37-5) + carbon monoxide (201230-82-2) + sodium tetraphenyl borate (143-66-8) → FeH(CO)(P(CH2CH2P(C6H5)2)3)(1+)*B(C6H5)4(1-)=[FeH(CO)(P(CH2CH2P(C6H5)2)3)][B(C6H5)4] (54477-77-9)

Guidance literature:

With CF₃SO₂OCH₃; In tetrahydrofuran; methanol; absence of air and moisture; addn. of MeOTf to Fe-complex (in THF), stirring under CO for 1 h, addn. of NaBPh4 (in MeOH); addn. of EtOH, crystn. on slow concn. (Ar-stream);

DOI:10.1021/ic960736q

Reference yield:

sodium tetrahydroborate (16940-66-2) + {FeCl(P(CH2CH2P(C6H5)2)3)}(1+)*B(C6H5)4(1-)={FeCl(P(CH2CH2P(C6H5)2)3)}B(C6H5)4 (118933-36-1) + carbon monoxide (201230-82-2) → {COFeH(P(CH2CH2P(C6H5)2)3)}(1+)*B(C6H5)4(1-)={COFeH(P(CH2CH2P(C6H5)2)3)}B(C6H5)4 (54477-77-9)

Guidance literature:

In ethanol; benzene; under CO atm.; filtrn. the reaction mixture, recrystallized from abs. ethanol/benzene;

DOI:10.1016/S0020-1693(00)93713-7

upstream raw materials:

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-H2)][BPh4]

[(P(CH2CH2PPh2)3)Fe(H)(η(2)-C2H4)][BPh4]

carbon monoxide

[FeH₂(P(CH₂CH₂P(C₆H₅)2)3)]