1,1,1-trifluoroacetone enolate anion

Base Information

• Chemical Name: 1,1,1-trifluoroacetone enolate anion
• CAS No.: 64723-97-3
• Molecular Formula: C₃H₂F₃O
• Molecular Weight: 111.043
• Mol file: 64723-97-3.mol

Synonyms:1,1,1-trifluoroacetone enolate anion

Chemical Property of 1,1,1-trifluoroacetone enolate anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1,1-trifluoroacetone enolate anion

There total 8 articles about 1,1,1-trifluoroacetone enolate anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1-trifluoro-2-propanone (421-50-1) + methanethiolate (17302-63-5) → methylthiol (74-93-1) + 1,1,1-trifluoroacetone enolate anion (64723-97-3)

Guidance literature:

Product distribution; Thermodynamic data; reaction enthalpy;

Reference yield:

1,1,1-trifluoro-2-propanone (421-50-1) + acetic acid methyl ester; deprotonated form (64723-96-2) → acetic acid methyl ester (79-20-9) + 1,1,1-trifluoroacetone enolate anion (64723-97-3)

Guidance literature:

at 24.9 ℃; Yield given;

DOI:10.1021/ja00217a002

Reference yield:

1,1,1-trifluoro-2-propanone (421-50-1) + 2-Methylallyl anion (64480-56-4) → 1,1,1-trifluoroacetone enolate anion (64723-97-3) + isobutene (115-11-7,15220-85-6)

Guidance literature:

Product distribution; Thermodynamic data; reaction enthalpy;

upstream raw materials:

1,1,1-trifluoro-2-propanone

acetone enolate ion

acetic acid ethyl ester; deprotonated form

acetaldehyde enolate

Downstream raw materials:

Ketene

trifluoromethan

trifluoromethanide

deprotonated ketene anion

Refernces

• 1、 Staneke, Paul O.,Ingemann, Steen,Nibbering, Nico M. M.. "Electron transfer as a possible initial step in nucleophilic addition elimination reactions between (radical) anions and carbonyl compounds in the gas phase". . p. 179 - 184. Retrieved 2007/10/03.
• 2、 McDonald, Richard N.,Chowdhury, A. Kesem. "Gas-Phase Nucleophilic Reactivities of Phenylnitrene (PhN-*) and Sulfur Anion Radicals (S-/.) at sp3 and Carbonyl Carbon". . p. 198 - 207. Retrieved 2007/10/02.