(E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane

Base Information

• Chemical Name: (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane
• CAS No.: 149902-39-6
• Molecular Formula: C₁₃H₂₄O₂Si
• Molecular Weight: 240.418
• Mol file: 149902-39-6.mol

Synonyms:(E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane

Chemical Property of (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane

There total 2 articles about (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Dimethyl-((E)-propenyl)-silanyl]-dimethyl-amine → (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane (149902-39-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; hexane / 3 h / Heating

2: 1.) t-BuLi / 1.) THF, hexane, RT, 1 h, 2.) THF, hexane, RT, 16 h

With tert.-butyl lithium; In tetrahydrofuran; hexane;

DOI:10.1021/ja00087a021

Reference yield:

(methoxymethyl)triphenylphosphonium chloride (4009-98-7) + 2-[Dimethyl-((E)-propenyl)-silanyloxy]-cyclohexanone (156684-39-8) → (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane (149902-39-6)

Guidance literature:

With tert.-butyl lithium; Yield given. Multistep reaction; 1.) THF, hexane, RT, 1 h, 2.) THF, hexane, RT, 16 h;

DOI:10.1021/ja00087a021

Reference yield: 33.0%

methanol (67-56-1) + (E and Z)-2-(dimethyl-1-propenylsiloxy)-1-(methoxymethylidene)cyclohexane (149902-39-6) → [(1S,2R)-2-Dimethoxymethyl-2-((E)-propenyl)-cyclohexyloxy]-methoxy-dimethyl-silane

Guidance literature:

With 2,6-dimethylpyridine; In tetrahydrofuran; electrolysis: reticulated vitreous carbon anode, 0.4 N LiClO₄;

DOI:10.1021/jo00065a003

upstream raw materials:

(methoxymethyl)triphenylphosphonium chloride

2-[Dimethyl-((E)-propenyl)-silanyloxy]-cyclohexanone