FERRIC BENZOATE

Base Information

• Chemical Name: FERRIC BENZOATE
• CAS No.: 14534-87-3
• Molecular Formula: C7H6 O2 . 1/3 Fe
• Molecular Weight: 298.078
• Hs Code.: 2916399090
• Mol file: 14534-87-3.mol

Synonyms:Benzoicacid, iron(3+) salt (8CI,9CI); Ferric benzoate; Iron benzoate, Fe(OBz)3;Iron(III) benzoate

Chemical Property of FERRIC BENZOATE

Chemical Property:

• Boiling Point: 249.3°Cat760mmHg
• Flash Point: 111.4°C
• PSA: 78.90000
• Density: g/cm³
• LogP: 3.92060

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Description: Ferric Benzoate is the ferric salt form of benzoate. Ferric benzoate has certain anti-corrosion properties. For example, it can be used as a novel steel corrosion inhibitor pigment for protective paint films. Ferric benzoate has been found particularly useful in providing intense, black permanent fingerprint records when used with the aforementioned metal complexing compounds

Technology Process of FERRIC BENZOATE

There total 6 articles about FERRIC BENZOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron (7439-89-6) + benzoic acid (65-85-0,8013-63-6) → dibenzoato iron(II) (14534-87-3) + iron(III) benzoate

Guidance literature:

With air; iodine; In toluene; ground metallic iron reacted with soln. of benzoic acid in toluene in bead mill with stirring in air in presence of stimulating iodine additive (catalyst); not isolated; Kinetics;

DOI:10.1134/S1070427208040058

Reference yield:

iron(III)-acetylacetonate (14024-18-1) → dibenzoato iron(II) (14534-87-3) + tetrabenzoato diacetylacetonato triiron(II)

Guidance literature:

With benzoic acid; In neat (no solvent); at 150°C;

Reference yield:

ferrocene (102-54-5,55404-68-7) + tert-Butyl peroxybenzoate (614-45-9) → dibenzoato iron(II) (14534-87-3) + iron(III) oxide

Guidance literature:

In benzene; byproducts: C5H5FeC5H4CH2C6H5; presence of toluene; small amt. of iron(II) benzoate;;

DOI:10.1016/S0040-4039(01)90642-2 DOI:10.1016/S0040-4020(01)98412-1

upstream raw materials:

ferrocene

tert-Butyl peroxybenzoate

dibenzoyl peroxide

benzoate

Refernces

• 1、 Spohn, Martin,Straehle, Joachim. "Benzoato Complexes of Iron and Cobalt. Synthesis and Properties of Fe3(C6H5COO)4(acac)2, Fe(C6H5COO)2 and Co(C6H5COO)2, Crystal Structure of Fe3(C6H5COO)4(acac)2 and Co(C6H5COO)2". . p. 540 - 546. Retrieved 2007/10/02.