Iron(III)Acetylacetonate

Base Information

• Chemical Name: Iron(III)Acetylacetonate
• CAS No.: 14024-18-1
• Molecular Formula: C15H21FeO6
• Molecular Weight: 353.175
• Hs Code.: 29420000
• European Community (EC) Number: 237-853-5
• Wikipedia: Tris(acetylacetonato)iron(III)
• Mol file: 14024-18-1.mol

Synonyms:Iron(III)Acetylacetonate;14024-18-1;SCHEMBL897914;NS00085359;Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)-

Chemical Property of Iron(III)Acetylacetonate

Chemical Property:

• Appearance/Colour: dark red powder
• Vapor Pressure: 0.174mmHg at 25°C
• Melting Point: 180-182 °C (dec.)(lit.)
• Boiling Point: 110 °C 2 mm
• Flash Point: 43.1ºC
• PSA: 102.42000
• Density: 5.24 g/mL at 25 °C(lit.)
• LogP: 1.66100
• Storage Temp.: Store below +30°C.
• Solubility.: Soluble in toluene.
• Water Solubility.: 2 g/L (20 ºC)
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 356.092224
• Heavy Atom Count: 22
• Complexity: 380

Purity/Quality:

99% ^*data from raw suppliers

Iron(III) acetylacetonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Fe]
• Uses: Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate. Iron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe2O4 Chemical Synthesis of Monodisperse Magnetic Nanoparticles

Technology Process of Iron(III)Acetylacetonate

There total 22 articles about Iron(III)Acetylacetonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

iron(III) chloride hexahydrate (121714-78-1,24290-40-2,58694-80-7,10025-77-1,64333-00-2) + potassium acetylacetonate (19393-11-4) → iron(III)-acetylacetonate (14024-18-1)

Guidance literature:

In ethanol; at pH 5-6 by the method of Fackler, Progress in Inorganic Chemistry, 1966, 7, 403; subliming twice (t=180 °C, P=5E-2 torr); elem. anal.;

Reference yield: 90.0%

iron(III) chloride (7705-08-0) + acetylacetone (123-54-6,81235-32-7) → iron(III)-acetylacetonate (14024-18-1)

Guidance literature:

With ammonia; In water; anhyd. FeCl3 dissolved in water, excess ammonia soln. added slowly withstirring and mixt heated on steam-bath for 15-20 min, Fe(OH)3 filtered off, washed with water and heated with acetylacetone on steam-bath for 35 min.; mixt. cooled, crystalsdried and recrystd. from ethanol; elem. anal.;

DOI:10.1039/DT9830000839

Reference yield: 80.0%

iron(III) chloride (7705-08-0) + sodium (Z)-4-oxopent-2-en-2-olate (1118-67-8) → iron(III)-acetylacetonate (14024-18-1)

Guidance literature:

In solid; byproducts: NaCl; mechanical treatment of the react. mixt. (FeCl3 (1.18 mmol) and an org.compd. (3.55 mmol)) in stainless steel reactors; the steel balls were used as an activating packing; in a dry box under N2; self-propagating synthesis; isolation by sublimation or extn.; elem. anal.; IR-spectroscopy; X-ray diffraction;

upstream raw materials:

acetylacetone

iron pentacarbonyl

iron(III) chloride hexahydrate

potassium acetylacetonate

Downstream raw materials:

trans-4-(4-methylcyclohexyl)-4-oxobutanoic acid

iron(II) oxide

iron

dibenzoato iron(II)

Refernces

Bioactivity of novel transition metal complexes of N′-[(4-methoxy)thiobenzoyl]benzoic acid hydrazide

10.1016/j.ejmech.2007.04.017

The study focuses on the synthesis and characterization of Cu(II), Fe(III), and Mn(II) complexes of a novel ligand, N-[(4-methoxy)thiobenzoyl]benzoic acid hydrazide (H2mtbh), and evaluates their bioactivity, particularly their cytotoxic effects on HT29 colon cancer cells and their ability to inhibit N-myristoyltransferase (NMT) activity. The chemicals used include the metal salts CuCl2$2H2O, Cu(OAc)2$H2O, Mn(OAc)2$4H2O, and Fe(acac)3, which react with H2mtbh to form the respective metal complexes. These complexes serve to investigate their potential as anticancer agents, with the aim of finding new drugs with different modes of action compared to existing chemotherapeutic drugs like cisplatin. The study also explores the effect of these metal complexes on the structural and kinetic properties involved in biological activity, as well as their interaction with DNA, enzymes, and proteins, which could contribute to their antitumor activity.