N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Base Information

Chemical Name:N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine
CAS No.:1377585-10-8
Molecular Formula:C₂₂H₂₉NO₅SSi
Molecular Weight:447.627
Hs Code.:

Synonyms:N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Suppliers and Price of N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

There total 4 articles about N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 1377585-42-6
N-[3-(tert-butyldimethylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

: 64-19-7,77671-22-8
acetic acid

: 1377585-10-8
N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Guidance literature:: With dipotassium peroxodisulfate; palladium diacetate; In chloroform; at 100 ℃; for 48h; air;
DOI:10.1002/chem.201200092

Reference yield:

: 4381-25-3
S-methyl-S-phenylsulfoximine

: 1377585-10-8
N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Guidance literature:: Multi-step reaction with 2 steps

1: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

2: dipotassium peroxodisulfate; palladium diacetate / chloroform / 48 h / 100 °C / air

With dmap; dipotassium peroxodisulfate; palladium diacetate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; chloroform;
DOI:10.1002/chem.201200092

Reference yield:

: 100-68-5
methyl-phenyl-thioether

: 1377585-10-8
N-[2-acetoxy-5-(tert-butyldiphenylsilyloxy)benzoyl]-S-methyl-S-phenylsulfoximine

Guidance literature:: Multi-step reaction with 4 steps

1.1: dihydrogen peroxide / water / 40 °C

2.1: sodium azide; sulfuric acid / chloroform / Inert atmosphere

2.2: 12 h / 0 - 45 °C

3.1: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

4.1: dipotassium peroxodisulfate; palladium diacetate / chloroform / 48 h / 100 °C / air

With dmap; dipotassium peroxodisulfate; sodium azide; sulfuric acid; dihydrogen peroxide; palladium diacetate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; chloroform; water;
DOI:10.1002/chem.201200092