cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

Base Information

Chemical Name:cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)
CAS No.:229626-20-4
Molecular Formula:C₂₂H₂₆Cl₂NPPt
Molecular Weight:601.415
Hs Code.:

Synonyms:cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

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Chemical Property of cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

Chemical Property:

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Technology Process of cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

There total 8 articles about cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: chloro(chloromethyl)(1,5-cyclo-octadiene)platinum(II)

: 51-80-9
bis-(dimethylamino)methane

: 603-35-0
triphenylphosphine

: 79328-82-8
cis-dichloro(dimethylaminomethylene)(triphenylphosphine)platinum(II)

: 229626-20-4
cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

Guidance literature:: In chloroform; N2-atmosphere; equimolar amts. of Pt-complex and PPh3, 2.5 equiv. of Me2NCH2NMe2, refluxing for 2 h, standing overnight at room temp.; chromy. (silica, TLC, MeOH:CH2Cl2 3:97); NMR-spectroscopy;
DOI:10.1021/om990049h

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: chloro(chloromethyl)(1,5-cyclo-octadiene)platinum(II)

: 4137-10-4
DIMCARB

: 603-35-0
triphenylphosphine

: 79328-82-8
cis-dichloro(dimethylaminomethylene)(triphenylphosphine)platinum(II)

: 229626-20-4
cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

Guidance literature:: In chloroform-d1; equimolar amts. of Pt-complex and PPh3, 2 equivs. of (Me2NH)2CO2, standing (3 h, room temp.), addn. of (H2CO)n (excess), shaking (12 days); not sepd., NMR-spectroscopy;
DOI:10.1021/om990049h

Reference yield:

: chloro(chloromethyl)(1,5-cyclo-octadiene)platinum(II)

: 4137-10-4
DIMCARB

: 603-35-0
triphenylphosphine

: 16841-99-9,25879-12-3,16902-93-5
trans-chlorohydridobis(triphenylphosphine)platinum(II)

: 79328-82-8
cis-dichloro(dimethylaminomethylene)(triphenylphosphine)platinum(II)

: 229626-09-9,333318-32-4
dichloro(triphenylphosphine)(dimethylamine)platinum(II)

: 229626-20-4
cis-dichloro[(trimethylammonio)methyl ylide](triphenylphosphine)platinum(II)

Guidance literature:: In chloroform-d1; equimolar amts. of Pt-complex and PPh3, 0.5 equiv. of dimethylammonium dimethylcarbamate, standing for 10 days; chromy. (silica, TLC, MeOH:CH2Cl2 3:97);
DOI:10.1021/om990049h