(Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

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Chemical Name:(Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene
CAS No.:251651-08-8
Molecular Formula:C₂₈H₄₆OSi₃
Molecular Weight:482.929
Hs Code.:

Synonyms:(Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

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Chemical Property of (Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

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Technology Process of (Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

There total 1 articles about (Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 113893-38-2
ω-trimethylsilylbutynylmagnesium chloride

: (R)-2-[(E)-3-(Dimethyl-phenyl-silanyl)-allyl]-5-methyl-cyclohex-2-enone

: 251651-08-8
(Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

Guidance literature:: With copper(l) iodide;
DOI:10.1021/ja992315o

Reference yield:

: 251651-08-8
(Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

: 9-benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-methyl-2,4,5,5a,6,7,8,9-octahydro-1H-cyclopenta[c]inden-4-ol

Guidance literature:: Multi-step reaction with 10 steps

1.1: NaI; mCPBA

2.1: 82 percent / Bu₃SnH; AIBN / benzene / Heating

3.1: Li; NH₃

4.1: TBAF

4.2: KHCO₃; H₂O₂ / methanol

5.1: 95 percent / imidazole

6.1: 90 percent / PCC

7.1: 88 percent / L-Selectride

8.1: 87 percent / KH / tetrahydrofuran

9.1: 82 percent / CF₃COOH

10.1: SeO₂ / dioxane

With 1H-imidazole; selenium(IV) oxide; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; ammonia; tri-n-butyl-tin hydride; lithium; potassium hydride; L-Selectride; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; trifluoroacetic acid; sodium iodide; In tetrahydrofuran; 1,4-dioxane; benzene; 1.1: Iodination / 2.1: Cyclization / 3.1: Reduction / 4.1: Substitution / 4.2: Oxidation / 5.1: silylation / 6.1: Oxidation / 7.1: Reduction / 8.1: benzylation / 9.1: desilylation / 10.1: allylic oxidation;
DOI:10.1021/ja992315o

Reference yield:

: 251651-08-8
(Dimethyl-{(E)-3-[(4R,6R)-4-methyl-6-(4-trimethylsilanyl-but-3-ynyl)-2-trimethylsilanyloxy-cyclohex-1-enyl]-propenyl}-silanyl)-benzene

: 251651-06-6
O-Benzoylpaniculatin

Guidance literature:: Multi-step reaction with 19 steps

1.1: NaI; mCPBA

2.1: 82 percent / Bu₃SnH; AIBN / benzene / Heating

3.1: Li; NH₃

4.1: TBAF

4.2: KHCO₃; H₂O₂ / methanol

5.1: 95 percent / imidazole

6.1: 90 percent / PCC

7.1: 88 percent / L-Selectride

8.1: 87 percent / KH / tetrahydrofuran

9.1: 82 percent / CF₃COOH

10.1: SeO₂ / dioxane

12.1: LiClO₄ / diethyl ether / 20 °C

13.1: aq. AcOH / tetrahydrofuran

14.1: 86 percent

15.1: (COCl)2

17.1: K₂CO₃ / xylene / Heating

18.1: LiAlH₄ / tetrahydrofuran

With 1H-imidazole; lithium aluminium tetrahydride; selenium(IV) oxide; oxalyl dichloride; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; ammonia; tri-n-butyl-tin hydride; lithium perchlorate; lithium; potassium hydride; L-Selectride; potassium carbonate; acetic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; trifluoroacetic acid; sodium iodide; In tetrahydrofuran; 1,4-dioxane; diethyl ether; xylene; benzene; 1.1: Iodination / 2.1: Cyclization / 3.1: Reduction / 4.1: Substitution / 4.2: Oxidation / 5.1: silylation / 6.1: Oxidation / 7.1: Reduction / 8.1: benzylation / 9.1: desilylation / 10.1: allylic oxidation / 11.1: Swern oxidation / 12.1: Addition / 13.1: desilylation / 14.1: Jones oxidation / 15.1: Chlorination / 16.1: Substitution / 17.1: Cyclization / 18.1: Reduction / 19.1: Swern oxidation;
DOI:10.1021/ja992315o