OsCl(PPh₃)(2,6-(PPh₂CH₂)₂C₆H₃)

Base Information

• Chemical Name: OsCl(PPh₃)(2,6-(PPh₂CH₂)₂C₆H₃)
• CAS No.: 293742-33-3
• Molecular Formula: C₅₀H₄₂ClOsP₃
• Molecular Weight: 961.458
• Mol file: 293742-33-3.mol

Synonyms:OsCl(PPh₃)(2,6-(PPh₂CH₂)₂C₆H₃)

Chemical Property of OsCl(PPh₃)(2,6-(PPh₂CH₂)₂C₆H₃)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of OsCl(PPh₃)(2,6-(PPh₂CH₂)₂C₆H₃)

There total 2 articles about OsCl(PPh₃)(2,6-(PPh₂CH₂)₂C₆H₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

dichlorotris(triphenylphosphine)osmium(II) (56586-93-7,40802-32-2) + 1,3-bis(diphenylphosphinomethyl)benzene (89756-88-7) → OsCl(PPh3)(2,6-(PPh2CH2)2C6H3) (293742-33-3)

Guidance literature:

In isopropyl alcohol; under N2 atm. mixt. 1,3-(PPh2CH2)2C6H4 and OsCl2(PPh3)3 in 2-propanol was refluxed for 8 h; solid was filtered, washed with 2-propanol and dried under vac. overnight; elem. anal.;

DOI:10.1021/om000150i

Reference yield: 50.0%

dichlorotris(triphenylphosphine)osmium(II) (56586-93-7,40802-32-2) + 1,3-bis(diphenylphosphinomethyl)benzene (89756-88-7) → OsCl(PPh3)(2,6-(PPh2CH2)2C6H3) (293742-33-3)

Guidance literature:

In isopropyl alcohol; for 24h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1016/j.poly.2014.06.051

Reference yield: 87.0%

OsCl(PPh3)(2,6-(PPh2CH2)2C6H3) (293742-33-3) + hydrogen (1333-74-0) → [OsCl(η2-H2)(P(C6H5)3)((C6H5)2PCH2C6H3CH2P(C6H5)2)] (468082-91-9)

Guidance literature:

In dichloromethane; (N2); standard Schlenk technique; soln. of Os complex in CH2Cl2 was attached to H2 ballon; mixt. was stirred at room temp. for 20 min; solvent removed (vac.); ether added; filtered; washed (ether); dried (vac., overnight); elem. anal.;

DOI:10.1016/S0020-1693(02)00750-8

upstream raw materials:

dichlorotris(triphenylphosphine)osmium(II)

1,3-bis(diphenylphosphinomethyl)benzene

Downstream raw materials:

[OsCl(η2-H2)(P(C6H5)3)((C6H5)2PCH2C6H3CH2P(C6H5)2)]

(osmium)μ-1,2-(η5-cyclopentadienyl)-(Ph)2-CH2(Ph)-2,6-(Ph2PCH2)2(C6H3)-Cl-chloride