[5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

Base Information

Chemical Name:[5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane
CAS No.:433283-78-4
Molecular Formula:C₁₅H₂₆OSi
Molecular Weight:250.456
Hs Code.:

Synonyms:[5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

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Chemical Property of [5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

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Technology Process of [5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

There total 3 articles about [5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 75-77-4
chloro-trimethyl-silane

: 433283-76-2
3,3-dimethyl-2-(2-methylprop-1-enylidene)cyclohexanone

: 433283-78-4
[5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

Guidance literature:: 3,3-dimethyl-2-(2-methylprop-1-enylidene)cyclohexanone; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; for 21h; Further stages.;
DOI:10.1021/jo010884k

Reference yield:

: 433283-74-0
3,3-dimethyl-2-(2-methylprop-1-enylidene)cyclohexanol

: 433283-78-4
[5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 89 percent / oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / -78 - 20 °C

2.1: lithium diisopropylamide / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 95 percent / tetrahydrofuran; hexane / 21 h

With oxalyl dichloride; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; 1.1: Swern oxidation;
DOI:10.1021/jo010884k

Reference yield:

: 4,4-dimethyl-3a-prop-1-ynylhexahydrobenzo[1,3]dioxol-2-one

: 433283-78-4
[5,5-dimethyl-6-(2-methylprop-1-enylidene)cyclohex-1-enyloxy]trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: copper(I) iodide / diethyl ether

1.2: 81 percent / diethyl ether / 5 h / 0 °C

2.1: 89 percent / oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / -78 - 20 °C

3.1: lithium diisopropylamide / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: 95 percent / tetrahydrofuran; hexane / 21 h

With copper(l) iodide; oxalyl dichloride; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; 2.1: Swern oxidation;
DOI:10.1021/jo010884k