Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone

Base Information

• Chemical Name: Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone
• CAS No.: 76886-55-0
• Molecular Formula: C₂₃H₃₂N₂O₂S
• Molecular Weight: 400.585
• Mol file: 76886-55-0.mol

Synonyms:Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone

Chemical Property of Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone

There total 2 articles about Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

trisylhydrazine (39085-59-1) + acetophenone (98-86-2) → C23H32N2O2S (76886-55-0)

Guidance literature:

DOI:10.1016/S0040-4039(01)82996-8

Reference yield: 90.0%

trisylhydrazine (39085-59-1) + acetophenone (98-86-2) → Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone (76886-55-0)

Guidance literature:

With hydrogenchloride; In methanol; for 1h; Ambient temperature;

DOI:10.1055/s-1982-29821

Reference yield: 90.0%

C17H28O3 + Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone (76886-55-0) → (E)-2,4,6-triisopropyl-N'-(1-phenylethylidene)-N-((2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienyl)-benzenesulfonohydrazide (1101861-77-1)

Guidance literature:

Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone; With potassium hydride; In tetrahydrofuran; mineral oil; at 23 ℃; for 0.25h; Inert atmosphere;

C₁₇H₂₈O₃; With bis(η3-allyl-μ-chloropalladium(II)); triphenylphosphine; In tetrahydrofuran; mineral oil; at 23 ℃; for 24h; Inert atmosphere;

DOI:10.1002/anie.200802921

upstream raw materials:

trisylhydrazine

acetophenone

Downstream raw materials:

α-n-propylstyrene

3-methyl-2-phenyl-1-pentene

1-isobutylvinylbenzene

2-phenylhex-1-ene

Refernces

• 1、 Fu, Xu-Fei,Xiang, Yu,Yu, Zhi-Xiang. "RhI-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes and CO by merging thermal and metal-catalyzed C-C bond cleavages". supporting information. p. 4242 - 4246. Retrieved 2015/03/14.
• 2、 Dudman, Christopher C.,Reese, Colin B.. "Preparation of Aryldiazoalkanes from 2,4,6-Triisopropylbenzenesulphonyl Hydrazones". . p. 419 - 421. Retrieved 2007/10/02.