Norformin deriv

Base Information

• Chemical Name: Norformin deriv
• CAS No.: 20826-80-6
• Molecular Formula: C12H16
• Molecular Weight: 160.259
• NSC Number: 244445
• UNII: FZR7L4HE95
• DSSTox Substance ID: DTXSID10311634
• Nikkaji Number: J789.882G
• Wikidata: Q82061506
• Mol file: 20826-80-6.mol

Synonyms:NORFORMIN DERIV;20826-80-6;Benzene, (1-methylenepentyl)-;2-Phenyl-1-hexene;WIN 34997;Styrene, .alpha.-butyl-;NSC 244445;NSC-244445;hex-1-en-2-ylbenzene;alpha-n-butylstyrene;.alpha.-Butylstyrene;(1-Butylvinyl)benzene;(1-Butylvinyl)benzene #;(hex-1-en-2-yl)benzene;FZR7L4HE95;1-HEXENE, 2-PHENYL-;DTXSID10311634;(1-METHYLENEPENTYL)BENZENE;NSC244445

Chemical Property of Norformin deriv

Chemical Property:

• Vapor Pressure: 0.123mmHg at 25°C
• Boiling Point: 226.4°Cat760mmHg
• Flash Point: 84.4°C
• Density: 0.867g/cm³
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 160.125200510
• Heavy Atom Count: 12
• Complexity: 129

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCC(=C)C1=CC=CC=C1

Technology Process of Norformin deriv

There total 41 articles about Norformin deriv which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

phenyl butyl ketone (1009-14-9) + Methyltriphenylphosphonium bromide (1779-49-3) → 2-phenylhex-1-ene (20826-80-6)

Guidance literature:

Methyltriphenylphosphonium bromide; With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

phenyl butyl ketone; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tet.2022.132651

Reference yield: 90.0%

1-phenyl-eth-1-en-1-yl diphenyl phosphate (50523-12-1) + butyl magnesium bromide (693-04-9) → 2-phenylhex-1-ene (20826-80-6)

Guidance literature:

With iron(III)-acetylacetonate; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; at 20 ℃; for 2h; chemoselective reaction;

DOI:10.1055/s-2008-1067194

Reference yield: 85.0%

5-hexen-2-ylbenzene (30134-52-2) → 2-phenylhex-1-ene (20826-80-6) + trans-hex-2-en-2-ylbenzene (20826-49-7) + 4-hexen-2-ylbenzene (5696-82-2)

Guidance literature:

With tantalum pentachloride; palladium dichloride; In 2-methyltetrahydrofuran; at 120 ℃; for 12h; chemoselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1039/c9cc00223e

upstream raw materials:

2-phenylhexan-2-ol

1-hexene

phenylmercuric acetate

(n-C₄H₉)(C₆H₅)CCHBClC₆H₅

Downstream raw materials:

phenyl butyl ketone

5-phenyl-2-pentanone

trans-hex-2-en-2-ylbenzene

(1-butylcyclopropyl)benzene

Refernces

• 1、 Avasthi, Kamlakar,Baba, Tsutomu,Suzuki, Akira. "The reaction of iodine with vinyltrialkylborates derived from trialkylboranes and trisylhydrazones of methyl ketones. A new method for synthesis of 1,1-dialkylethenes". . p. 945 - 946. Retrieved 1980.
• 2、 Zhao, Bin,Pan, Zichen,Zhu, Anqiao,Yue, Yanni,Ma, Mengtao,Xue, Fei. "Electrochemical fluorosulfonylation of alkenes to access vicinal fluorinated sulfones derivatives". supporting information. . Retrieved 2022/01/24.
• 3、 Han, Xiaoli,Nie, Xiaodi,Feng, Yiman,Wei, Bangguo,Si, Changmei,Lin, Guoqiang. "Intermolecular [4 + 2] process of N-acyliminium ions with simple olefins for construction of functional substituted-1,3-oxazinan-2-ones". supporting information. p. 3526 - 3530. Retrieved 2021/06/12.