bis(ferrocenyl acetylide)mercury

Base Information

• Chemical Name: bis(ferrocenyl acetylide)mercury
• CAS No.: 94619-64-4
• Molecular Formula: C₂₄H₁₈Fe₂Hg
• Molecular Weight: 618.691
• Mol file: 94619-64-4.mol

Synonyms:bis(ferrocenyl acetylide)mercury

Chemical Property of bis(ferrocenyl acetylide)mercury

Chemical Property:

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Technology Process of bis(ferrocenyl acetylide)mercury

There total 3 articles about bis(ferrocenyl acetylide)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.8%

ferroceneacetylene (1271-47-2) + mercury(II) diacetate (1600-27-7) → acetylferrocene (1271-55-2) + (α-methoxyvinyl)ferrocene (94598-12-6) + bis(ferrocenyl acetylide)mercury (94619-64-4)

Guidance literature:

With methanol; In methanol; byproducts: CH3OCH3, CH3CO2H, CH3OHgOC(O)CH3; mercuric acetate in anhydrous methanol added dropwise (over a period of10-15 min) to a stirred soln. of ethynylferrocene at room temp. under N2, pptd., 0 min, molar ratio of FcCCH/Hg(OAc)2: 0.48/0.22; filtered off, evapd., 1.: residue chromd. on silica gel (40-70°C/petroleum ether and diethyl ether) or 2.: dissolved with CH2Cl2, washedwith water, dried over anhydrous Na2SO4, concd., chromd. on silica gel,GC, elem anal.;

DOI:10.1021/om00123a001

Reference yield: 50.0%

ferroceneacetylene (1271-47-2) + mercury(II) diacetate (1600-27-7) → acetylferrocene (1271-55-2) + bis(ferrocenyl acetylide)mercury (94619-64-4)

Guidance literature:

With acetic acid; In tetrahydrofuran; byproducts: (CH3C(O)O)2Hg, (CH3CO)2O; mercuric acetate dissolved in THF with a drop of AcOH, soln. added dropwise to a stirred soln. of ethynylferrocene at room temp. under N2, 2 h,pptd., stirred further 3 h; filtered off, washed with THF;

DOI:10.1021/om00123a001

Reference yield: 26.0%

ferroceneacetylene (1271-47-2) + mercury(II) diacetate (1600-27-7) → acetylferrocene (1271-55-2) + bis(ferrocenyl acetylide)mercury (94619-64-4) + fc-C(=CH2)-OOC-CH3

Guidance literature:

With acetic acid; In acetic acid; byproducts: (CH3C(O)O)2Hg, (CH3CO)2O; mercuric acetate in anhydrous acetic acid added dropwise to a stirred soln. of ethynylferrocene, stirred for 1.5 h; filtered off, solvent removed under vacuum, treated with diethyl ether,evapd.;

DOI:10.1021/om00123a001

upstream raw materials:

ferroceneacetylene

mercury(II) diacetate

Downstream raw materials:

acetylferrocene