4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

Base Information

Chemical Name:4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl
CAS No.:1365543-30-1
Molecular Formula:C₃₇H₄₄N₇O₅
Molecular Weight:666.8
Hs Code.:

4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

Synonyms:4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

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Chemical Property of 4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

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Technology Process of 4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

There total 11 articles about 4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 1365543-39-0
2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carboxylic acid

: 14691-88-4,78774-22-8
4-amino-2,2,6,6-tetramethyl-1-piperidine-1-oxyl

: 1365543-30-1
4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

Guidance literature:: With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In N,N-dimethyl-formamide; at 20 ℃; for 30h;
DOI:10.1016/j.bmcl.2012.01.042

Reference yield:

: 1365543-35-6
2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}-5-[(1-methoxy-1-methylamino)carbonyl]benzimidazole

: 1365543-30-1
4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

Guidance literature:: Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / tetrahydrofuran / 3 h / -78 - 0 °C

2: sodium metabisulfite / ethanol; water / 12 h / Reflux

3: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / N,N-dimethyl-formamide / 30 h / 20 °C

With sodium metabisulfite; diisobutylaluminium hydride; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In tetrahydrofuran; ethanol; water; N,N-dimethyl-formamide;
DOI:10.1016/j.bmcl.2012.01.042

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 1365543-30-1
4-{[2-(2-{4-[2-(1,1-dimethylethoxycarbonylamino)ethoxy]phenyl}benzimidazol-5-yl)benzimidazole-5-carbonyl]amino}-2,2,6,6-tetramethylpiperidin-1-oxyl

Guidance literature:: Multi-step reaction with 6 steps

1: tetrahydrofuran / 4 h / 20 °C

2: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 12 h / 20 °C

3: sodium metabisulfite / ethanol; water / 2 h / Reflux

4: diisobutylaluminium hydride / tetrahydrofuran / 3 h / -78 - 0 °C

5: sodium metabisulfite / ethanol; water / 12 h / Reflux

6: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / N,N-dimethyl-formamide / 30 h / 20 °C

With sodium metabisulfite; diisobutylaluminium hydride; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; ethanol; water; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.bmcl.2012.01.042