di(4-methoxyphenyl)iodonium triflate

Base Information

• Chemical Name: di(4-methoxyphenyl)iodonium triflate
• CAS No.: 1429318-45-5
• Molecular Formula: C₁₅H₁₄F₃IO₅S
• Molecular Weight: 490.239
• Mol file: 1429318-45-5.mol

Synonyms:di(4-methoxyphenyl)iodonium triflate

Chemical Property of di(4-methoxyphenyl)iodonium triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di(4-methoxyphenyl)iodonium triflate

There total 16 articles about di(4-methoxyphenyl)iodonium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

trifluorormethanesulfonic acid (1493-13-6) + methoxybenzene (100-66-3) → di(4-methoxyphenyl)iodonium triflate (1429318-45-5)

Guidance literature:

methoxybenzene; With iodine; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 20h;

trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/chem.201703057

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + C16H17IO4 → di(4-methoxyphenyl)iodonium triflate (1429318-45-5)

Guidance literature:

In dichloromethane; at 0 - 20 ℃; for 0.333333h;

DOI:10.1080/00397911.2016.1181764

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + 4-methoxy(diacetoxyiodo)benzene (16308-14-8) + 4-methoxyphenylboronic acid (5720-07-0) → di(4-methoxyphenyl)iodonium triflate (1429318-45-5)

Guidance literature:

4-methoxyphenylboronic acid; With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.166667h;

4-methoxy(diacetoxyiodo)benzene; In dichloromethane; at 20 ℃;

trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 0.333333h;

DOI:10.1021/acs.joc.6b01390

upstream raw materials:

para-iodoanisole

1-Iodonaphthalene

iodobenzene

4-methoxy(diacetoxyiodo)benzene

Downstream raw materials:

benzo[d]oxazol-2-yl(4-methoxy phenyl)methanone

C₂₇H₂₅N₃O₃

4-methoxyphenyl trifluoromethylsulfide

methyl 4-(trifluoromethyl)phenyl ether