16308-14-8

Basic information

• Product Name: 4-methoxy(diacetoxyiodo)benzene
• Synonyms: 4-methoxy(diacetoxyiodo)benzene
• CAS NO: 16308-14-8
• Molecular Weight: 352.126
• Mol File: 16308-14-8.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: 4-methoxy(diacetoxyiodo)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy(diacetoxyiodo)benzene(16308-14-8)
• EPA Substance Registry System: 4-methoxy(diacetoxyiodo)benzene(16308-14-8)

Safety Data

• Hazardous Substances Data: 16308-14-8(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 31599-50-5 4-methoxy(dichloroiodo)benzene 
• 127-09-3 sodium acetate 
• 6293-71-6 4,4'-dimethoxydiphenyliodonium iodide 
• 75-07-0 acetaldehyde 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 2754-27-0 trimethylsilyl acetate 

Downstream Products

• 102987-40-6 (3-(4-methoxyphenyl)prop-1-ynyl)trimethylsilane 
• 139553-93-8 [3-(2-Iodo-5-methoxy-phenyl)-prop-1-ynyl]-trimethyl-silane 
• 160893-38-9 C₁₆H₁₁IN₂O₄ 
• 23383-01-9 (Dibenzoylmethan)-(4-methoxyphenyl)-iodonium-betain 
• 126550-93-4 <(hydroxy)(tosyloxy)iodo>-p-methoxybenzene 
• 1694-19-5 p-methoxystilbene 
• 53484-54-1 3-(4-methoxyphenyl)prop-2-enyl acetate 
• 696-62-8 para-iodoanisole 
• 832-01-9 methyl p-methoxycinnamate 
• 141339-54-0 bis(4-anisyl)iodonium triflate 
• 1039396-21-8 (E)-3-((4-methoxyphenyl)(phenyl)methylene)-1-methylindolin-2-one 

Relevant articles and documents

Functionalization of closo-borates via iodonium zwitterions

A simple method for the functionalization of closo-borates [closo-B10H10]2- (1), [closo-1-CB9H10]- (2), [closo-B12H12]2- (3), [closo-1-CB11H

Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts

A novel approach to the preparation of imidazole-substituted cyclic iodonium salts has been developed via the oxidative cyclization of 1-phenyl-5-iodoimidazole using a cheap and available Oxone/H2SO4 oxidative system. The structure of the new polycyclic heteroarenes has been confirmed by single-crystal X-ray diffractometry, revealing the characteristic structure features for cyclic iodonium salts. The newly produced imidazole-flanked cyclic iodonium compounds were found to readily engage in a heterocyclization reaction with elemental sulfur, affording benzo[5,1-b]imidazothiazoles in good yields.

Aryl naproxen derivative high-valence iodine compound, preparation method and application thereof

The invention discloses an aryl naproxen derivative high-valence iodine compound, a preparation method and application thereof, wherein a series of naproxen derivatives are prepared through preparation and derivatization of naproxen high-valence iodine co

Oxidase catalysis via aerobically generated hypervalent iodine intermediates

The development of sustainable oxidation chemistry demands strategies to harness O'2 as a terminal oxidant. Oxidase catalysis, in which O'2 serves as a chemical oxidant without necessitating incorporation of oxygen into reaction products, would allow diverse substrate functionalization chemistry to be coupled to O'2 reduction. Direct O'2 utilization suffers from intrinsic challenges imposed by the triplet ground state of O'2 and the disparate electron inventories of four-electron O'2 reduction and two-electron substrate oxidation. Here, we generate hypervalent iodine reagents - a broadly useful class of selective two-electron oxidants - from O'2. This is achieved by intercepting reactive intermediates of aldehyde autoxidation to aerobically generate hypervalent iodine reagents for a broad array of substrate oxidation reactions. The use of aryl iodides as mediators of aerobic oxidation underpins an oxidase catalysis platform that couples substrate oxidation directly to O'2 reduction. We anticipate that aerobically generated hypervalent iodine reagents will expand the scope of aerobic oxidation chemistry in chemical synthesis.