[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

Base Information

• Chemical Name: [HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4
• CAS No.: 754227-14-0
• Molecular Formula: C₂₂H₂₄NOPRe*C₂₄H₂₀B
• Molecular Weight: 854.853

Synonyms:[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

Chemical Property of [HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

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Technology Process of [HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

There total 1 articles about [HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[HRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[Re(CO)2(C5H4C2H4N(CH3)CH2P(C6H5)2)] (754227-12-8) + sodium tetraphenyl borate (143-66-8) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → [HRe(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)](1+)*B(C6H5)4(1-)=[HRe(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)]B(C6H5)4 (754227-14-0)

Guidance literature:

In dichloromethane; byproducts: CO; a soln. of acid added at 0°C (3 portions, 5 min, 1.2 equiv.) to astirred soln. of Re compd., stirred for 20 min, solvent evapd., dissolv ed (methanol), a soln. of B compd. added; centrifuged, ppt. washed (methanol), recrystd. (acetone/methanol); elem.anal.;

DOI:10.1002/ejic.200300650

Reference yield: 91.0%

[HRe(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)](1+)*B(C6H5)4(1-)=[HRe(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)]B(C6H5)4 (754227-14-0) + allyl bromide (106-95-6) → [C3H5Re(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)](1+)*B(C6H5)4(1-)=[C3H5Re(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)]B(C6H5)4 (754227-16-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; a soln. of Li compd. (1.2 equiv., hexane) added (0°C, 1 min) to asuspn. of Re compd. (THF), stirred for 20 min, allylbromide added, stir red at room. temp. for 1 h; concd. (vac.), washed (methanol), recrystd. (CH2Cl2/methanol); elem. anal.;

DOI:10.1002/ejic.200300650

Reference yield: 85.0%

[HRe(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)](1+)*B(C6H5)4(1-)=[HRe(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)]B(C6H5)4 (754227-14-0) + benzyl bromide (100-39-0) → [C6H5CH2Re(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)](1+)*B(C6H5)4(1-)=[C6H5CH2Re(CO)(C5H4C2H4N(CH3)CH2P(C6H5)2)]B(C6H5)4 (754227-24-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; a soln. of Li compd. (1.2 equiv., hexane) added (0°C, 1 min) to asuspn. of Re compd. (THF), stirred for 20 min, benzylbromide added, sti rred at room. temp. for 1 h; concd. (vac.), washed (methanol, diethyl ether), recrystd. (acetone/hexane); elem. anal.;

DOI:10.1002/ejic.200300650

upstream raw materials:

[Re(CO)2(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]

sodium tetraphenyl borate

3-chloro-benzenecarboperoxoic acid

Downstream raw materials:

[CH₃Re(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[CH₃Re(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

[C₃H₅Re(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[C₃H₅Re(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

[BrRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[BrRe(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

[C₆H₅CH₂Re(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[C₆H₅CH₂Re(CO)(C₅H₄C₂H₄N(CH₃)CH₂P(C₆H₅)2)]B(C₆H₅)4

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