[(2,4,6-tri-tert-butylpyridineH)][HB(C₆F₅)3]

Base Information

• Chemical Name: [(2,4,6-tri-tert-butylpyridineH)][HB(C₆F₅)3]
• CAS No.: 1187326-96-0
• Molecular Formula: C₁₇H₂₉N*C₁₈HBF₁₅*H
• Molecular Weight: 761.425
• Mol file: 1187326-96-0.mol

Synonyms:[(2,4,6-tri-tert-butylpyridineH)][HB(C₆F₅)3]

Chemical Property of [(2,4,6-tri-tert-butylpyridineH)][HB(C₆F₅)3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,4,6-tri-tert-butylpyridineH)][HB(C₆F₅)3]

There total 2 articles about [(2,4,6-tri-tert-butylpyridineH)][HB(C₆F₅)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,4,6-tri-tertbutylpyridine (20336-15-6) + tris(pentafluorophenyl)borate (1109-15-5) → [(2,4,6-tri-tert-butylpyridineH)][HB(C6F5)3] (1187326-96-0)

Guidance literature:

With hydrogen; In toluene; at 20 ℃; for 24h; under 750.075 Torr;

DOI:10.1021/om100951a

Reference yield: 38.0%

2,4,6-tri-tertbutylpyridine (20336-15-6) + hydrogen (1333-74-0) + bis(pentafluorophenyl)borohydride (165612-94-2) → [H2B(C6F5)]2 (1187326-94-8,1187326-95-9) + [(2,4,6-tri-tert-butylpyridineH)][HB(C6F5)3] (1187326-96-0)

Guidance literature:

In toluene; under N2; B-contg. compd. (0.2 mmol) and 2,4,6-tri-tert-butylpyridine (0.2 mmol) were dissolved in toluene; the vessel was filled with H2 (1 bar); stirring at 120°C for 24 h; the mixt. was concd. to half of its vol.; hexane was added for pptn.; the mixt. was filtered, washed with hexane and dried in vac.; elem. anal.;

DOI:10.1021/om900517d

upstream raw materials:

2,4,6-tri-tertbutylpyridine

tris(pentafluorophenyl)borate

hydrogen

bis(pentafluorophenyl)borohydride